التفاصيل البيبلوغرافية
| العنوان: |
Schiff Base Conjugated Carbon Nitride-Supported PdCoNi Nanoparticles for Enhanced Formic Acid Dehydrogenation |
| المؤلفون: |
Yiru Wu (4343164), Yawen Li (1415497), Xiaofen Chen (8568687), Guifang Li (5003849), Hongyuan Huang (11256401), Lishan Jia (1760716) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Pharmacology, Ecology, Cancer, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, Schiff base groups, electron-rich Pd species, dehydrogenation, FA, TOF, decomposition, NP, Schiff Base Conjugated Carbon Nitri., Schiff base, catalyst, carbon nitride support |
| الوصف: |
An effective and low-cost nanocatalyst is designed for formic acid (FA) dehydrogenation to boost practical applications. Herein, we report superior PdCoNi nanoparticles (NPs) supported on Schiff base conjugated carbon nitride, which exhibits excellent catalytic performance with a turnover frequency (TOF) of 1308 h –1 on FA decomposition to hydrogen at room temperature. The results show that the Schiff base groups grafted on the carbon nitride support contribute to providing abundant conjugated active sites for anchoring metal, leading to the formation of ultrafine and well-dispersed PdCoNi NPs (1.70 nm) with electron-rich Pd species, which are responsible for the outstanding catalytic activity. The conjugated Schiff base can also facilitate the O–H bond dissociation on FA, which further promotes the decomposition of FA. This low-cost and high-performance palladium-based catalyst is conducive to the development of composite catalysts on FA dehydrogenation. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Schiff_Base_Conjugated_Carbon_Nitride-Supported_PdCoNi_Nanoparticles_for_Enhanced_Formic_Acid_Dehydrogenation/15144224 |
| DOI: |
10.1021/acs.iecr.1c02749.s001 |
| الاتاحة: |
https://doi.org/10.1021/acs.iecr.1c02749.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.79493D26 |
| قاعدة البيانات: |
BASE |