Academic Journal
Magnetic properties and 1 H NMR spectroscopy of TM 2 2+ [W IV (CN) 8 ]·nH 2 O
| العنوان: | Magnetic properties and 1 H NMR spectroscopy of TM 2 2+ [W IV (CN) 8 ]·nH 2 O |
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| المؤلفون: | Kováč, J., Zentková, M., Bokor, M., Mihalik, M., Kavečanský, V., Mitróová, Z., Zentko, A., Pekker, A., Kamarás, K. |
| المصدر: | physica status solidi c ; volume 3, issue 1, page 130-133 ; ISSN 1862-6351 1610-1642 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2006 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | We report on magnetic properties of bimetallic extended networks built from [W IV (CN) 8 ] 4– and TM 2+ = Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ , Cu 2+ , Zn 2+ . The weak exchange interaction is the reason for appearance of magnetically ordered state at low temperatures for all compounds with exception of Zn 2 [W(CN) 8 ].nH 2 O. It has been shown that susceptibility data for all compounds, except Co 2 [W(CN) 8 ].5H 2 O, follows the Curie Weiss law above T = 50 K. For Co 2 [W(CN) 8 ].5H 2 O the modified Curie Weiss law is valid. Free induction decay (FID) signals showed behaviour peculiar to paramagnetic samples. The decayed more rapidly in a higher applied static magnetic field B 0 = ω 0 / γ 1H . (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/pssc.200562481 |
| الاتاحة: | http://dx.doi.org/10.1002/pssc.200562481 http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpssc.200562481 https://onlinelibrary.wiley.com/doi/pdf/10.1002/pssc.200562481 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.75B99DB3 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/pssc.200562481 |
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