التفاصيل البيبلوغرافية
| العنوان: |
Multi-Stage Redox Systems Based on Dicationic P-Containing Polycyclic Aromatic Hydrocarbons |
| المؤلفون: |
Delouche, Thomas, Vacher, Antoine, Caytan, Elsa, Roisnel, Thierry, Le Guennic, Boris, Jacquemin, Denis, Hissler, Muriel, Bouit, Pierre-Antoine |
| بيانات النشر: |
American Chemical Society (ACS) |
| سنة النشر: |
2019 |
| الوصف: |
In this communication, we report the straightforward synthesis of unprecedented electron-acceptors based on dicationic P-containing PAHs (Polycyclic Aromatic Hydrocarbons) where two phosphoniums are connected through various PAHs backbones. The impact of pi-extension on both the optical and redox properties is investigated using a joint experimental/theoretical approach. Finally, (spectro)-electrochemical studies prove that these compounds possess three redox states and EPR studies confirms the in situ formation of an organic radical. |
| نوع الوثيقة: |
other/unknown material |
| اللغة: |
unknown |
| DOI: |
10.26434/chemrxiv.11364935 |
| الاتاحة: |
http://dx.doi.org/10.26434/chemrxiv.11364935
https://ndownloader.figshare.com/files/20177960 |
| Rights: |
https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: |
edsbas.742851F5 |
| قاعدة البيانات: |
BASE |