التفاصيل البيبلوغرافية
| العنوان: |
Photoionization efficiency spectrum and ionization energy of C2H5SO |
| المؤلفون: |
Cheng, BM, Hung, WC, Chen, WC, Yu, CH, Lee, YP |
| المساهمون: |
游靜惠 |
| بيانات النشر: |
American Institute of Physics |
| سنة النشر: |
1997 |
| المجموعة: |
National Tsing Hua University Institutional Repository (NTHUR) |
| مصطلحات موضوعية: |
CH3S, KINETICS, NO2, O3, ATMOSPHERE, 298-K |
| Time: |
31 |
| الوصف: |
2010305010026 ; 化學系 ; The photoionization efficiency (PIE) spectrum of C2H5SO was measured in the spectral range 110-150 nm by means of a photoionization mass spectrometer coupled to a synchrotron radiation source. C2H5SO radicals were generated by reacting O atoms with C2H5SC2H5 or C2H5SSC2H5 in a discharge Bow tube. The ionization energy of C2H5SO was determined to be (8.71+/-0.02) eV, in agreement with theoretical calculations of 8.8 eV for ionization from C2H5SO to singlet C2H5SO+ using the G2 method, PIE spectrum also shows a sharp increase at 10.0 eV, corresponding to the ionization energy from C2H5SO to triplet C2H5SO+ predicted by theory. Theoretical calculations also predict two stable conformers with sim;lar energies for each of C2H5SO, singlet C2H5SO+, and tripler C2H5SO+, respectively; these conformers are indistinguishable in our experiments. |
| نوع الوثيقة: |
journal/newspaper |
| اللغة: |
English |
| تدمد: |
0021-9606 |
| Relation: |
JOURNAL OF CHEMICAL PHYSICS, American Institute of Physics, Volume 107, Issue 21, DEC 1 1997, Pages 8794-8799; http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57088 |
| الاتاحة: |
http://nthur.lib.nthu.edu.tw/dspace/handle/987654321/57088 |
| رقم الانضمام: |
edsbas.70E530F7 |
| قاعدة البيانات: |
BASE |