التفاصيل البيبلوغرافية
| العنوان: |
Meniscus-Guided 3D Microprinting of Pure Metal–Organic Frameworks with High Gas-Uptake Performance |
| المؤلفون: |
Yu Liu (6938), Jihyuk Yang (9444600), Chaoran Tao (12009937), Heekwon Lee (9444591), Mojun Chen (5130230), Zhaoyi Xu (1870552), Huiren Peng (2850893), Xiao Huan (10968326), Jie Li (15030), Xing Cheng (348361), Ji Tae Kim (2102155) |
| سنة النشر: |
2022 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Medicine, Molecular Biology, Sociology, Cancer, Space Science, Environmental Sciences not elsewhere classified, Information Systems not elsewhere classified, structural design freedom, monoliths produced using, involve rheological additives, high spatial resolution, high material performance, guided 3d microprinting, 1 monolith displays, 3d printing approaches, high gas, uptake performance, guided three, 1 micro, technique enables, resulting hkust, pure hkust, practical use, method exploits, mechanical forces, highly confine, guide supersaturation, driven crystallization, 3 μm |
| الوصف: |
Metal–organic frameworks (MOFs) are a promising nanoporous functional material system; however, the practicality of shaping freeform MOF monoliths, while retaining their porosity, remains a challenge. Here, we demonstrate that meniscus-guided three-dimensional (3D) printing can produce pure MOF monoliths with high gas-uptake performance. The method exploits a femtoliter precursor ink meniscus to highly confine and guide supersaturation-driven crystallization in a layer-by-layer manner to print a pure HKUST-1 micro-monolith with a high spatial resolution of <3 μm. The proposed 3D printing technique does not involve rheological additives, binders, or mechanical forces. Thus, the resulting HKUST-1 monolith displays a prominently high Brunauer–Emmett–Teller surface area of 1192 m 2 /g, which is superior to monoliths produced using other 3D printing approaches. This technique enables both structural design freedom and high material performance in the manufacturing of MOFs for practical use. |
| نوع الوثيقة: |
dataset |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/media/Meniscus-Guided_3D_Microprinting_of_Pure_Metal_Organic_Frameworks_with_High_Gas-Uptake_Performance/19082377 |
| DOI: |
10.1021/acsami.1c22582.s002 |
| الاتاحة: |
https://doi.org/10.1021/acsami.1c22582.s002 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.7092F9E2 |
| قاعدة البيانات: |
BASE |