Academic Journal
Alkyl chain length influence of the functionalized diethanolamine ligand on the slow relaxation of the magnetization in {CoIII3DyIII3} complexes
| العنوان: | Alkyl chain length influence of the functionalized diethanolamine ligand on the slow relaxation of the magnetization in {CoIII3DyIII3} complexes |
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| المؤلفون: | Bonnenfant, Chloë, Vadra, Nahir, Rouzières, Mathieu, Clérac, Rodolphe, Cukiernik, Fabio, D, Alborés, Pablo |
| المساهمون: | Facultad de Ciencias Exactas y Naturales Buenos Aires (FCEyN), Universidad de Buenos Aires Buenos Aires (UBA), Centre de Recherche Paul Pascal (CRPP), Université de Bordeaux (UB)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS), CNRS, Université de Bordeaux, Région Nouvelle Aquitaine, Quantum Matter Bordeaux |
| المصدر: | ISSN: 1477-9226. |
| بيانات النشر: | CCSD Royal Society of Chemistry |
| سنة النشر: | 2024 |
| المجموعة: | Université de Montpellier: HAL |
| مصطلحات موضوعية: | Molecular Magnetism, heterometallic complexes, Co complexes, Dy complexes, Magnetic complex, Crystal structure, [CHIM.COOR]Chemical Sciences/Coordination chemistry, [CHIM]Chemical Sciences, [CHIM.INOR]Chemical Sciences/Inorganic chemistry, [CHIM.MATE]Chemical Sciences/Material chemistry, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat] |
| الوصف: | International audience ; We report the synthesis, structural characterization and magnetic properties of a series of Co(III)/Dy(III)complexes built up from an N-alkyl derivatized amino-alcohol ligand diethanolamine, functionalized withC H alkyl chains (n = 3, 4, 6, 8 and 10). While n = 3 afforded a butterfly {CoIIIDyIII} core, the other alkyl n 2n+1 2 2chains (n = 4, 6, 8) afforded hexanuclear triangle-in-triangle {CoIIIDyIII} complexes as shown by single- 33crystal X-ray determinations. Infrared spectroscopy allows us to characterize the C10 derivative complex, which did not crystallize. Magnetic ac susceptibility data collected below 10 K at driving frequencies up to 10 kHz under zero-dc field and up to 1 T provide insight into the SMM behaviour of the studied com- plexes. The characteristic time of the magnetization dynamics can be understood in terms of the com- peting Raman, Direct and Orbach-like mechanisms. A relationship between the magnetization dynamics within the family of complexes and the increasing alkyl chain length is discussed. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1039/d3dt03656a |
| الاتاحة: | https://hal.science/hal-04445243 https://hal.science/hal-04445243v1/document https://hal.science/hal-04445243v1/file/24,%20Dalton,%2057%20HAL.pdf https://doi.org/10.1039/d3dt03656a |
| Rights: | info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: | edsbas.6FEACC8F |
| قاعدة البيانات: | BASE |
| DOI: | 10.1039/d3dt03656a |
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