Academic Journal
Synthesis of 1,1,4,4‐Tetracyanobuta‐1,3‐Dienes using Tetracyanoethylene Oxide via [3+2]‐Cycloaddition‐Ring Opening Reaction
| العنوان: | Synthesis of 1,1,4,4‐Tetracyanobuta‐1,3‐Dienes using Tetracyanoethylene Oxide via [3+2]‐Cycloaddition‐Ring Opening Reaction |
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| المؤلفون: | Dar, Arif Hassan, Gowri, Vijayendran, Neethu, K. M., Jayamurugan, Govindasamy |
| المصدر: | ChemistrySelect ; volume 5, issue 40, page 12437-12441 ; ISSN 2365-6549 2365-6549 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2020 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Unlike the [3+2] cycloadduct of electron‐donating group (EDG)‐free alkynes with tetracyanoethylene oxide (TCNEO), the EDG induced [3+2] cycloadduct underwent one‐pot ring‐opening and deoxygenation reactions to provide the established EDG‐substituted non‐planar 1,1,4,4‐tetracyanobuta‐1,3‐dienes (TCBDs) push‐pull chromophores. This is an alternate synthetic method that provides access to TCBDs other than the [2+2] cycloaddition–retroelectrocyclization reactions with tetracyanoethene. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/slct.202003179 |
| الاتاحة: | http://dx.doi.org/10.1002/slct.202003179 https://onlinelibrary.wiley.com/doi/pdf/10.1002/slct.202003179 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/slct.202003179 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.6E5CB37A |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/slct.202003179 |
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