Academic Journal
A Silylene Stabilized by a σ‐Donating Nickel(0) Fragment
| العنوان: | A Silylene Stabilized by a σ‐Donating Nickel(0) Fragment |
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| المؤلفون: | Frutos, María, Parvin, Nasrina, Baceiredo, Antoine, Madec, David, Saffon‐merceron, Nathalie, Branchadell, Vicenç, Kato, Tsuyoshi |
| المساهمون: | Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA), Institut de Chimie de Toulouse (ICT), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS), Université de Toulouse (UT), Universitat Autònoma de Barcelona = Autonomous University of Barcelona = Universidad Autónoma de Barcelona (UAB), ANR-21-CE07-0018,MMdash,Nouveaux complexes binucléaires hybrides(2021), ANR-18-CE07-0044,Si-POP,Une nouvelle stratégie pour le développement de la nanochimie du silicium et du carbone(2018) |
| المصدر: | ISSN: 1433-7851. |
| بيانات النشر: | HAL CCSD Wiley-VCH Verlag |
| سنة النشر: | 2022 |
| المجموعة: | Université Toulouse III - Paul Sabatier: HAL-UPS |
| مصطلحات موضوعية: | [CHIM.COOR]Chemical Sciences/Coordination chemistry |
| الوصف: | International audience ; A donor-stabilized silylene 4 featuring a Ni 0based donating ligand was synthesized. Complex 4 exhibits a pyramidalized and nucleophilic Si II center and shows a peculiar behavior due to the cooperative reactivity of Si and Ni centers. Calculations indicate that the orientation of Ni-ligands with respect to the silylene moiety is crucial in determining the role of the Nifragment (Lewis acid or Lewis base) towards silylene. Indeed, a simple 90°rotation of the SiÀ Ni bond, reverses the role of Ni, and transforms a classical silylene!Ni 0 complex into an unprecedented Ni 0 !silylene complex. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | hal-03823525; https://hal.science/hal-03823525; https://hal.science/hal-03823525/document; https://hal.science/hal-03823525/file/Si-Ni%20complex%20Angew%202022%20KATO.pdf |
| DOI: | 10.1002/anie.202201932 |
| الاتاحة: | https://hal.science/hal-03823525 https://hal.science/hal-03823525/document https://hal.science/hal-03823525/file/Si-Ni%20complex%20Angew%202022%20KATO.pdf https://doi.org/10.1002/anie.202201932 |
| Rights: | info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: | edsbas.6D408BF2 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/anie.202201932 |
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