Academic Journal
The Interplay Between Component Denticity and Flexibility Promotes the Formation of [Ag I ⋅⋅⋅Ag I ]‐stabilised Links and Knots
| العنوان: | The Interplay Between Component Denticity and Flexibility Promotes the Formation of [Ag I ⋅⋅⋅Ag I ]‐stabilised Links and Knots |
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| المؤلفون: | Sarwa, Aleksandra, Khmara, Andrei, Konieczny, Krzysztof A., Kulesza, Dagmara, Zych, Eugeniusz, Trzaskowski, Bartosz, Szyszko, Bartosz |
| المساهمون: | Narodowe Centrum Nauki |
| المصدر: | Angewandte Chemie International Edition ; ISSN 1433-7851 1521-3773 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2025 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | A subtle interplay between the flexibility of the 2,2’‐bipyridyl‐based diamine and the denticity of the coordination domain formed upon self‐assembly enabled the formation of four distinct topologies stabilised by [Ag⋅⋅⋅Ag] 2+ pairs. The reactions utilising 2,6‐diformylpyridine resulted in the formation of silver(I)‐stabilised molecular tweezer, trefoil knot, and Solomon link. The 1,8‐naphthyridine‐based dialdehyde promoted the formation of [2]catenanes and trefoil knot, demonstrating very close Ag I ⋅⋅⋅Ag I distances. Two of the studied assemblies demonstrated interesting luminescent properties in the solid state. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/anie.202423962 |
| الاتاحة: | https://doi.org/10.1002/anie.202423962 https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202423962 |
| Rights: | http://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: | edsbas.6D18A59D |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/anie.202423962 |
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