التفاصيل البيبلوغرافية
| العنوان: |
Surface Site-Specific Replacement for Catalysis Selectivity Switching |
| المؤلفون: |
Jun Zha (2735284), Xiangfu Meng (1931626), Wentao Fan (696181), Qing You (494016), Nan Xia (600675), Wanmiao Gu (8212620), Yan Zhao (58882), Lin Hu (562273), Jin Li (119007), Haiteng Deng (138991), Hui Wang (30400), Nan Yan (266514), Zhikun Wu (843291) |
| سنة النشر: |
1753 |
| مصطلحات موضوعية: |
Molecular Biology, Evolutionary Biology, Ecology, Cancer, Infectious Diseases, Computational Biology, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, nanoparticles including nanoclusters, fundamental scientific research, density functional theory, defined metal nanoclusters, 2 , surface metal site, specific antigalvanic replacement, surface site, specific replacement, surface replacement, replacing ag, practical applications, materials without, first reported, electrocatalytic reduction, dependent selectivity, calculations describe, atomic precision |
| الوصف: |
Surface atom replacement in materials without other composition/structure changes is challenging but is important for fundamental scientific research and for practical applications. In particular, for nanoparticles including nanoclusters, surface metal site-specific replacement with atomic precision has not yet been achieved. In this study, we for the first time achieved surface site-specific antigalvanic replacement with the remaining composition/structure and surface replacement-dependent selectivity in the electrocatalytic reduction of CO 2 . Density functional theory (DFT) calculations describe the catalysis selectivity switch induced by replacing Ag with Cu and explain why Cu replacement facilitates C 2 production. Also, CO 2 electroreduction to C 2 on well-defined metal nanoclusters is first reported in this study. |
| نوع الوثيقة: |
dataset |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/dataset/Surface_Site-Specific_Replacement_for_Catalysis_Selectivity_Switching/21843419 |
| DOI: |
10.1021/acsami.2c18553.s002 |
| الاتاحة: |
https://doi.org/10.1021/acsami.2c18553.s002 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.6BDB83CB |
| قاعدة البيانات: |
BASE |