Academic Journal
Anilate Tethered Neutral Tetrahedral Pd(II) Cages Exhibiting Selective Encapsulation of Xylenes and Mesitylene
| العنوان: | Anilate Tethered Neutral Tetrahedral Pd(II) Cages Exhibiting Selective Encapsulation of Xylenes and Mesitylene |
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| المؤلفون: | Yadav, Ashok, Sarkar, Meghamala, Subrahmanyam, Sappati, Chaudhary, Atul, Hey‐Hawkins, Evamarie, Boomishankar, Ramamoorthy |
| المساهمون: | Science and Engineering Research Board, Erasmus+ |
| المصدر: | Chemistry – A European Journal ; volume 26, issue 19, page 4209-4213 ; ISSN 0947-6539 1521-3765 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2020 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | The design of porous materials for the recognition of multiple hydrocarbons is highly desirable for the energy‐efficient separation and recognition of chemical feedstock. Herein, three new iso‐structural porous discrete metal–organic cages of formula {[Pd 3 (N i Pr) 3 PO] 4 (R‐AN) 6 } (R‐AN=anilate linkers) for the selective recognition of substituted aromatic hydrocarbons are reported. The tetrahedral cages 1 , 2 , and 3 containing anilate, chloranilate, and bromanilate linkers exhibited selective encapsulation of mesitylene, o ‐xylene, and p ‐xylene, respectively, over other analogous aromatic hydrocarbons. These selective encapsulations were driven by the variations in the portal diameters present at each of these cages and their interactions with the hydrocarbon guests. These observations are supported by mass spectrometry, NMR studies, and theoretical binding‐energy calculations. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/chem.201905852 |
| الاتاحة: | http://dx.doi.org/10.1002/chem.201905852 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201905852 https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201905852 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.201905852 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.6B682E22 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/chem.201905852 |
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