Formalizing the mechanism of the allylic substitution reaction (S N '):Application to the highly enantio- and diastereo-selective syntheses of 1-phenyl-2-vinylcyclopentanes

التفاصيل البيبلوغرافية
العنوان:	Formalizing the mechanism of the allylic substitution reaction (S N '):Application to the highly enantio- and diastereo-selective syntheses of 1-phenyl-2-vinylcyclopentanes
المؤلفون:	Krief, Alain, Wouters, Johan, Norberg, Bernadette, Kremer, Adrian
المصدر:	Krief , A , Wouters , J , Norberg , B & Kremer , A 2018 , ' Formalizing the mechanism of the allylic substitution reaction (S N ') : Application to the highly enantio- and diastereo-selective syntheses of 1-phenyl-2-vinylcyclopentanes ' , ARKIVOC , vol. 2018 , no. 5 , pp. 308-333 . https://doi.org/10.24820/ark.5550190.p010.571
سنة النشر:	2018
المجموعة:	Research Portal - University of Namur / Portail de la recherche de l'Université de Namur
مصطلحات موضوعية:	Aryl cyclopentanes, Benzyl selenides, Se/Li exchange, SN' reaction, Stereospecific carbocyclization
الوصف:	We report efficient stereoselective and high yielding syntheses of each of the four enantiomers of phenylcyclopentanes bearing a quaternary center and a E-propenyl chain on the adjacent carbon that involves intramolecular allylic substitution reactions. In complement to its synthetic value, this process models the S N ' reaction and allows prediction of its stereochemical outcome.
نوع الوثيقة:	article in journal/newspaper
وصف الملف:	application/pdf
اللغة:	English
DOI:	10.24820/ark.5550190.p010.571
الاتاحة:	https://researchportal.unamur.be/en/publications/477994fe-cbf5-44a9-b5b7-67b4ad725729 https://doi.org/10.24820/ark.5550190.p010.571 https://pure.unamur.be/ws/files/37894671/2018_KriefWoutersNorbergKremer_article.pdf http://www.scopus.com/inward/record.url?scp=85052636131&partnerID=8YFLogxK
Rights:	info:eu-repo/semantics/openAccess
رقم الانضمام:	edsbas.6A75283A
قاعدة البيانات:	BASE

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الوصف
DOI:	10.24820/ark.5550190.p010.571