التفاصيل البيبلوغرافية
| العنوان: |
Straightforward access to multifunctional pi-conjugated P-heterocycles |
| المؤلفون: |
Delouche, Thomas, Caytan, Elsa, Cordier, Marie, Roisnel, Thierry, Taupier, Grégory, Molard, Yann, Vanthuyne, Nicolas, Le Guennic, Boris, Hissler, Muriel, Jacquemin, Denis, Bouit, Pierre-Antoine |
| بيانات النشر: |
American Chemical Society (ACS) |
| سنة النشر: |
2022 |
| الوصف: |
We report the straightforward one-pot synthesis of 5 or 6-membered P-heterocycles featuring internal ylidic bond: P-containing acenaphthylenes and phenanthrenes. The stability of the compounds tolerates post-functionalization through direct arylation to introduce electron-rich/poor substituents and the synthetic strategy is also compatible with the preparation of more elaborated polyaromatic scaffolds such acenes and helicenes. Using a joint experimental and theoretical approach, we show that the molecular engineering of this platform allows not only tuning their absorption/emission on the entire visible range but also endowing them with chiroptical or non-linear optical properties, making them valuable dyes for a large panel of photonic or opto-electronic applications. |
| نوع الوثيقة: |
other/unknown material |
| اللغة: |
unknown |
| DOI: |
10.26434/chemrxiv-2022-69z8f |
| الاتاحة: |
http://dx.doi.org/10.26434/chemrxiv-2022-69z8f
https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/622f139c968f5293f5ba5a88/original/straightforward-access-to-multifunctional-pi-conjugated-p-heterocycles.pdf |
| Rights: |
https://creativecommons.org/licenses/by-nc/4.0/ |
| رقم الانضمام: |
edsbas.6889690C |
| قاعدة البيانات: |
BASE |