التفاصيل البيبلوغرافية
| العنوان: |
Na 2 Ga 7 : A Zintl-Wade Phase Related to “α-Tetragonal Boron' |
| المؤلفون: |
Yu, C., Ormeci, A., Veremchuk, I., Feng, X., Prots, Y., Krnel, M., Koželj, P., Schmidt, M., Burkhardt, U., Böhme, B., Akselrud, L., Baitinger, M., Grin, Y. |
| المصدر: |
Inorganic Chemistry |
| سنة النشر: |
2023 |
| المجموعة: |
Max Planck Society: MPG.PuRe |
| الوصف: |
Na2Ga7 crystallizes with the orthorhombic space group Pnma (no. 62; a = 14.8580(6) Å, b = 8.6766(6) Å, and c = 11.6105(5) Å; Z = 8) and constitutes a filled variant of the Li2B12Si2 structure type. The crystal structure consists of a network of icosahedral Ga12 units with 12 exohedral bonds and four-bonded Ga atoms in which the Na atoms occupy the channels and cavities. The atomic arrangement is consistent with the Zintl [(4b)Ga]− and Wade [(12b)Ga12]2- electron counting approach. The compound forms peritectically from Na7Ga13 and the melt at 501 °C and does not show a homogeneity range. The band structure calculations predict semiconducting behavior consistent with the electron balance [Na+]4[(Ga12)2-][Ga-]2. Magnetic susceptibility measurements show that Na2Ga7 is diamagnetic. © 2023 The Authors. Published by American Chemical Society. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| Relation: |
http://hdl.handle.net/21.11116/0000-000D-667F-3 |
| الاتاحة: |
http://hdl.handle.net/21.11116/0000-000D-667F-3 |
| رقم الانضمام: |
edsbas.65E5ED2F |
| قاعدة البيانات: |
BASE |