التفاصيل البيبلوغرافية
| العنوان: |
Nondestructive Direct Optical Patterning of Perovskite Nanocrystals with Carbene-Based Ligand Cross-Linkers |
| المؤلفون: |
Dan Liu, Kangkang Weng, Haifeng Zhao, Song Wang, Hengwei Qiu, Xiyu Luo, Shaoyong Lu, Lian Duan, Sai Bai, Hao Zhang, Jinghong Li |
| سنة النشر: |
1753 |
| المجموعة: |
Smithsonian Institution: Figshare |
| مصطلحات موضوعية: |
Genetics, Biotechnology, Inorganic Chemistry, Plant Biology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, Information Systems not elsewhere classified, advanced device platforms, 16 %, among, direct optical patterning, charge transport properties, rationally designed carbene, method produces high, colloidal perovskite nanocrystals, based ligand cross, linkers microscale patterning, perovskite nanocrystals, based cross, photochemical properties, electrical properties, prototype light, performance light, optoelectronic devices, nc patterns, maximum luminance, linkers need, level electronic, existing approaches |
| الوصف: |
Microscale patterning of colloidal perovskite nanocrystals (NCs) is essential for their integration in advanced device platforms, such as high-definition displays. However, perovskite NCs usually show degraded optical and/or electrical properties after patterning with existing approaches, posing a critical challenge for their optoelectronic applications. Here we achieve nondestructive, direct optical patterning of perovskite NCs with rationally designed carbene-based cross-linkers and demonstrate their applications in high-performance light-emitting diodes. We reveal that both the photochemical properties and the electronic structures of cross-linkers need to be carefully tailored to the material properties of perovskite NCs. This method produces high-resolution (∼4000 ppi) NC patterns with preserved photoluminescent quantum efficiencies and charge transport properties. Prototype light-emitting diodes with patterned/cross-linked NC layers show a maximum luminance of over 60000 cd m –2 and a peak external quantum efficiency of 16%, among the highest for patterned perovskite electroluminescent devices. Such a material-adapted patterning method enabled by designs from a photochemistry perspective could foster the applications of perovskite NCs in system-level electronic and optoelectronic devices. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Nondestructive_Direct_Optical_Patterning_of_Perovskite_Nanocrystals_with_Carbene-Based_Ligand_Cross-Linkers/25250385 |
| DOI: |
10.1021/acsnano.3c07975.s001 |
| الاتاحة: |
https://doi.org/10.1021/acsnano.3c07975.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.659050DA |
| قاعدة البيانات: |
BASE |