Academic Journal
Confronting the Issues Associated with the Practical Implementation of Zinc Blende-type SiC Anodes for Efficient and Reversible Storage of Lithium Ions
| العنوان: | Confronting the Issues Associated with the Practical Implementation of Zinc Blende-type SiC Anodes for Efficient and Reversible Storage of Lithium Ions |
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| المؤلفون: | Ravi Nandan, Noriyuki Takamori, Koichi Higashimine, Rajashekar Badam, Noriyoshi Matsumi |
| سنة النشر: | 2024 |
| مصطلحات موضوعية: | Biophysics, Biochemistry, Medicine, Biotechnology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, viable anodic material, sup >+, post 175 cycles, peers like si, minimum volumetric expansion, overall study suggests, comprehensive structural studies, 128th cycle ), ∼ 930 mah, zinc blende system, reversible specific capacity, commercially available licoo, 2 , type sic anodes, zinc blende, study shows, structural robustness, reversible storage, lib ), capacity retention, based anodes, ∼ 79, ∼ 53 |
| الوصف: | Electrochemically active zinc blende anodic materials have been envisioned to host Li + ions at tetrahedrally configured interstitial sites, resulting in minimum volumetric expansion. Despite the silicon carbide (β-SiC) being a zinc blende system with a high theoretical specific capacity (∼1430 mAh/g) and structural robustness, it has not been studied to the extent that its other peers like Si/graphite/Sn/Al, etc. have been. By identifying and addressing the issues that currently limit commercially available β-SiC’s practically achivable storage ability, we can unlock its potential as a viable anodic material for Li + -ion battery (LIB). In this work, comprehensive structural studies on commercially procured different batches of β-SiC unveil the presence of a native suboxide passivation layer. This suboxide layer adversely affects the Li + -ions diffusion kinetics besides poor initial Coulombic efficiency and inferior reversible capacity (∼79 mAh/g @ 128th cycle). The removal of this suboxide passivation layer immediately brings a 5-fold increase in Li + -ions diffusion kinetics and an ∼53% increase in the first reversible specific capacity. The study shows the need for further assistance to increase the Li + -ions diffusion, and the surface modification by N-doped carbon is found to be competent enough to bring an ∼35-fold increase in overall lithium diffusion kinetics. This results in a noticeable increase in reversible specific capacity by more than an order of magnitude from ∼79 to ∼930 mAh/g. The modified SiC-based anodes are found to be compatible when paired with commercially available LiCoO 2 in full-cells. The LiCoO 2 //SiC-based full cell demonstrates the capacity retention of nearly 80% post 175 cycles and is well capable of powering prototype portable electronic devices, too. The overall study suggests that commercially available silicon carbide materials are worthy of consideration as negative electrodes in LIB upon deliberate surface engineering and should be given a chance. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | unknown |
| Relation: | https://figshare.com/articles/journal_contribution/Confronting_the_Issues_Associated_with_the_Practical_Implementation_of_Zinc_Blende-type_SiC_Anodes_for_Efficient_and_Reversible_Storage_of_Lithium_Ions/25347711 |
| DOI: | 10.1021/acsaem.3c02676.s001 |
| الاتاحة: | https://doi.org/10.1021/acsaem.3c02676.s001 https://figshare.com/articles/journal_contribution/Confronting_the_Issues_Associated_with_the_Practical_Implementation_of_Zinc_Blende-type_SiC_Anodes_for_Efficient_and_Reversible_Storage_of_Lithium_Ions/25347711 |
| Rights: | CC BY-NC 4.0 |
| رقم الانضمام: | edsbas.5F6D75C5 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1021/acsaem.3c02676.s001 |
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