التفاصيل البيبلوغرافية
| العنوان: |
Electrospinning of ZIF-67 Derived Co-C-N Composite Efficiently Activating Peroxymonosulfate to Degrade Dimethyl Phthalate |
| المؤلفون: |
Guowei Pang, Min Ji, Zhuoran Li, Zhengwu Yang, Xiaojie Qiu, Yingxin Zhao |
| المصدر: |
Water; Volume 14; Issue 14; Pages: 2248 |
| بيانات النشر: |
Multidisciplinary Digital Publishing Institute |
| سنة النشر: |
2022 |
| المجموعة: |
MDPI Open Access Publishing |
| مصطلحات موضوعية: |
elctrospinning, ZIF-67, peroxymonosulfate, cobalt leaching control |
| جغرافية الموضوع: |
agris |
| الوصف: |
In this work, an efficient cage-core peroxymonosulfate (PMS) catalyst was synthesized by applying an electrospinning–calcination process to the cobalt–zeolitic imidazole framework (ZIF-67) crystals for the catalytic degradation of dimethyl phthalate (DMP). The morphology and surface properties of the synthesized materials (ZIF-67, Z600 and ZP400/600/800) were well characterized. ZP600 showed great performance for the catalytic degradation of DMP in the initial pH range of 7.5–10.5. The removal rate of DMP could reach 90.4% in 60 min under optimum dosages of reagents (catalyst = 0.1 g/L, PMS = 0.5 mM, DMP = 6 ppm), and the mineralization degree of contaminant could reach 65%. By quenching experiments, it was determined that sulfate radical (SO4−·) and hydroxyl radical (·OH) dominated the degradation process. Moreover, due to the good magnetism, ZP600 could be easily separated from liquid and showed great reusability in five-cycle reaction experiments. Surprisingly, with the cover of cage-like polyacrylonitrile (PAN) fibers, the cobalt leaching amount of ZP600 decreased by about 87%. This study would expand the application of the electrospinning process in the development of functional materials for water purification. |
| نوع الوثيقة: |
text |
| وصف الملف: |
application/pdf |
| اللغة: |
English |
| Relation: |
Wastewater Treatment and Reuse; https://dx.doi.org/10.3390/w14142248 |
| DOI: |
10.3390/w14142248 |
| الاتاحة: |
https://doi.org/10.3390/w14142248 |
| Rights: |
https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: |
edsbas.5D7FC432 |
| قاعدة البيانات: |
BASE |