التفاصيل البيبلوغرافية
| العنوان: |
Recent Synthesis Developments of Organoboron Compounds via Metal-Free Catalytic Borylation of Alkynes and Alkenes |
| المؤلفون: |
Yanmei Wen, Chunmei Deng, Jianying Xie, Xinhuang Kang |
| المصدر: |
Molecules; Volume 24; Issue 1; Pages: 101 |
| بيانات النشر: |
Multidisciplinary Digital Publishing Institute |
| سنة النشر: |
2018 |
| المجموعة: |
MDPI Open Access Publishing |
| مصطلحات موضوعية: |
organoboron compound, metal-free catalytic boration, nucleophilic boron, alkyne, alkene |
| جغرافية الموضوع: |
agris |
| الوصف: |
Diboron reagents have been traditionally regarded as “Lewis acids”, which can react with simple Lewis base to create a significant nucleophilic character in one of boryl moieties. In particular, bis(pinacolato)diboron (B2pin2) reacts with simple Lewis bases, such as N-heterocyclic carbenes (NHCs), phosphines and alkoxides. This review focuses on the application of trivalent nucleophilic boryl synthon in the selective preparation of organoboron compounds, mainly through metal-free catalytic diboration and the β-boration reactions of alkynes and alkenes. |
| نوع الوثيقة: |
text |
| وصف الملف: |
application/pdf |
| اللغة: |
English |
| Relation: |
Organic Chemistry; https://dx.doi.org/10.3390/molecules24010101 |
| DOI: |
10.3390/molecules24010101 |
| الاتاحة: |
https://doi.org/10.3390/molecules24010101 |
| Rights: |
https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: |
edsbas.5BF528B0 |
| قاعدة البيانات: |
BASE |