Academic Journal

Recovering Metals from Aqueous Solutions by Biosorption onto Hydrolyzed Olive Cake

التفاصيل البيبلوغرافية
العنوان: Recovering Metals from Aqueous Solutions by Biosorption onto Hydrolyzed Olive Cake
المؤلفون: Rafael Fernández-González, María Ángeles Martín-Lara, Gabriel Blázquez, Antonio Pérez, Mónica Calero
المصدر: Water; Volume 11; Issue 12; Pages: 2519
بيانات النشر: Multidisciplinary Digital Publishing Institute
سنة النشر: 2019
المجموعة: MDPI Open Access Publishing
مصطلحات موضوعية: biosorption, heavy metals, hydrothermal treatment, olive cake, wastewater treatment
جغرافية الموضوع: agris
الوصف: Olive cake obtained as a by-product from the olive oil industry has been evaluated as biosorbent of heavy metals from aqueous solutions in batch and continuous systems (fixed-bed columns). First, a complete study of effect of hydrothermal treatment with water on biosorption capacity of resulting solid was performed. Results showed that the values of biosorption capacity increased when the particle size of material decreased and the temperature of treatment increased. Then, hydrolyzed olive cake was treated by common chemicals (hot water, nitric acid, and sodium hydroxide) and the impact of chemical treatment was analyzed. The results were well reproduced by Langmuir and Freundlich isotherm models, getting maximum experimental biosorption capacities that changed between 42.34 mg/g obtained for the solid material modified by NaOH and 14.27 mg/g obtained for the solid material modified by nitric acid. Finally, laboratory tests in fixed-bed columns were performed with four different heavy metals and at three different inlet concentrations. The biosorption capacity increased from 2.83 mg/g (Cr), 4.51 mg/g (Cu), 12.30 mg/g (Pb), and 4.10 mg/g (Zn) to 3.08 mg/g (Cr), 5.17 mg/g (Cu), 13.21 mg/g (Pb), and 5.51 mg/g (Zn) when the concentration of metal ions increased, from 50 mg/L to 200 mg/L, respectively. Also, the experimental data obtained was successfully correlated with the Thomas, Yoon–Nelson, and dose–response models.
نوع الوثيقة: text
وصف الملف: application/pdf
اللغة: English
Relation: Wastewater Treatment and Reuse; https://dx.doi.org/10.3390/w11122519
DOI: 10.3390/w11122519
الاتاحة: https://doi.org/10.3390/w11122519
Rights: https://creativecommons.org/licenses/by/4.0/
رقم الانضمام: edsbas.5A81F15F
قاعدة البيانات: BASE