Academic Journal
European Journal of Inorganic Chemistry / Small Neutral Geminal Silicon/Phosphorus Frustrated Lewis Pairs
| العنوان: | European Journal of Inorganic Chemistry / Small Neutral Geminal Silicon/Phosphorus Frustrated Lewis Pairs |
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| المؤلفون: | Kinder, Timo, Blomeyer, Sebastian, Franke, Maurice, Depenbrock, Felix, Neumann, Beate, Stammler, Hans-Georg, Mitzel, Norbert W. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Frustrated Lewis Pairs, Silicon, Phosphorus, Fluorinated substituents, Gas electron diffraction |
| الوصف: | Two new silicon/phosphorus-based frustrated Lewis pairs (FLP), F3SiCH2PtBu2 (1) and Cl3SiCH2PtBu2 (2) were prepared from lithiated di-tert-butylmethylphosphane, LiCH2PtBu2, and the corresponding silicon tetrahalides. They were characterised by NMR spectroscopy and by single-crystal X-ray diffraction. A gas phase electron diffraction study of 1 identified two conformers of similar energy in the vapor. The reactivity of both, 1 and 2, towards a series of small molecules was investigated. Phenyl isocyanate was found to undergo addition reactions of its C-N unit to afford five-membered SiCPC(O)N-ring structures. Cl3SiCH2PtBu2 (2) was converted with perfluorophenyllithium and 3,5-bis(trifluoromethyl)phenyllithium. The reaction with LiC6F5 resulted in the ortho-fluoride substitution product (C6F5)(2)SiCH2(C6F4)PtBu2 (5), while the aryl reagent without ortho-fluoride groups, leads to the intramolecular Lewis pair (C8H3F6)(3)SiCH2PtBu2 (6). The FLP reactivity of 6 was tested. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| تدمد: | 1434-1948 |
| Relation: | vignette : https://noah.nrw/titlepage/urn/urn:nbn:de:0070-pub-29377308/128; eIssn:1099-0682; ISI:000485478600001; urn:nbn:de:0070-pub-29377308; https://nbn-resolving.org/urn:nbn:de:0070-pub-29377308; system:bielefeld_pub_2937730 |
| DOI: | 10.1002/ejic.201900929 |
| الاتاحة: | https://nbn-resolving.org/urn:nbn:de:0070-pub-29377308 https://doi.org/10.1002/ejic.201900929 https://noah.nrw/doi/10.1002/ejic.201900929 |
| Rights: | cc-by-nc_4 |
| رقم الانضمام: | edsbas.598F7D91 |
| قاعدة البيانات: | BASE |
| تدمد: | 14341948 |
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| DOI: | 10.1002/ejic.201900929 |