Academic Journal
Correlation between structural and solution calorimetric data for Cp*Ru(PR3)(2)Cl (Cp* = C5Me5) complexes
| العنوان: | Correlation between structural and solution calorimetric data for Cp*Ru(PR3)(2)Cl (Cp* = C5Me5) complexes |
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| المؤلفون: | Smith, D C, Haar, C M, Luo, L B, Li, C B, Cucullu, M E, Mahler, C H, Nolan, Steven Patrick, Marshall, W J, Jones, N L, Fagan, P J |
| المصدر: | Smith , D C , Haar , C M , Luo , L B , Li , C B , Cucullu , M E , Mahler , C H , Nolan , S P , Marshall , W J , Jones , N L & Fagan , P J 1999 , ' Correlation between structural and solution calorimetric data for Cp*Ru(PR3)(2)Cl (Cp* = C5Me5) complexes ' , Organometallics , vol. 18 , no. 12 , pp. 2357-2361 . https://doi.org/10.1021/om990090k |
| سنة النشر: | 1999 |
| مصطلحات موضوعية: | TERTIARY PHOSPHINE-LIGANDS, ORGANORUTHENIUM THERMOCHEMISTRY, PHOSPHORUS LIGANDS, ENTHALPIES, SUBSTITUTION, ENERGIES, SYSTEM, MONODENTATE, CHEMISTRY, FRAGMENT |
| الوصف: | Single-crystal X-ray diffraction studies were conducted bn the following compounds: Cp*Ru(PMe3)(2)Cl (1), Cp*Ru(PPhMe2)(2)Cl (2), Cp*Ru(PMePh2)(2)Cl (3), Cp*Ru(PPh3)(2)Cl (4), Cp*Ru(PEt3)(2)Cl (5), Cp*Ru(AsEt3)(2)Cl (6), Cp*Ru((PBu3)-Bu-n)(2)Cl (7), and Cp*Ru(dmpm)Cl (8). Structural information obtained from these X-ray studies can be correlated with enthalpies of ligand substitution previously determined from solution calorimetry. The cone angle of the phosphine ligand (monodentate) and the Ru-P bond distance were found to be proportional to the enthalpy of reaction. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1021/om990090k |
| الاتاحة: | https://risweb.st-andrews.ac.uk/portal/en/researchoutput/correlation-between-structural-and-solution-calorimetric-data-for-cprupr32cl-cp--c5me5-complexes(545a72b4-5af7-491c-9239-ff0d8847bcf1).html https://doi.org/10.1021/om990090k |
| Rights: | info:eu-repo/semantics/restrictedAccess |
| رقم الانضمام: | edsbas.58325597 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1021/om990090k |
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