التفاصيل البيبلوغرافية
| العنوان: |
Oxidative Bio-Desulfurization by Nanostructured Peroxidase Mediator System |
| المؤلفون: |
Eliana Capecchi, Davide Piccinino, Bruno Mattia Bizzarri, Lorenzo Botta, Marcello Crucianelli, Raffaele Saladino |
| المصدر: |
Catalysts; Volume 10; Issue 3; Pages: 313 |
| بيانات النشر: |
Multidisciplinary Digital Publishing Institute |
| سنة النشر: |
2020 |
| المجموعة: |
MDPI Open Access Publishing |
| مصطلحات موضوعية: |
oxidative bio-desulfurization, lignin nanoparticles, horseradish peroxidase, dibenzothiophene |
| الوصف: |
Bio-desulfurization is an efficient technology for removing recalcitrant sulfur derivatives from liquid fuel oil in environmentally friendly experimental conditions. In this context, the development of heterogeneous bio-nanocatalysts is of great relevance to improve the performance of the process. Here we report that lignin nanoparticles functionalized with concanavalin A are a renewable and efficient platform for the layer-by-layer immobilization of horseradish peroxidase. The novel bio-nanocatalysts were applied for the oxidation of dibenzothiophene as a well-recognized model of the recalcitrant sulfur derivative. The reactions were performed with hydrogen peroxide as a green primary oxidant in the biphasic system PBS/n-hexane at 45 °C and room pressure, the highest conversion of the substrate occurring in the presence of cationic polyelectrolyte layer and hydroxy-benzotriazole as a low molecular weight redox mediator. The catalytic activity was retained for more transformations highlighting the beneficial effect of the support in the reusability of the heterogeneous system. |
| نوع الوثيقة: |
text |
| وصف الملف: |
application/pdf |
| اللغة: |
English |
| Relation: |
Biocatalysis; https://dx.doi.org/10.3390/catal10030313 |
| DOI: |
10.3390/catal10030313 |
| الاتاحة: |
https://doi.org/10.3390/catal10030313 |
| Rights: |
https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: |
edsbas.540CF962 |
| قاعدة البيانات: |
BASE |