Academic Journal
Lanthanide-Based Complexes Containing a Chiral trans-1,2-Diaminocyclohexane (DACH) Backbone: Spectroscopic Properties and Potential Applications
| العنوان: | Lanthanide-Based Complexes Containing a Chiral trans-1,2-Diaminocyclohexane (DACH) Backbone: Spectroscopic Properties and Potential Applications |
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| المؤلفون: | Piccinelli F., Nardon C., Bettinelli M., Melchior A., Tolazzi M., Zinna F., Di Bari L. |
| المساهمون: | Piccinelli, F., Nardon, C., Bettinelli, M., Melchior, A., Tolazzi, M., Zinna, F., Di Bari, L. |
| سنة النشر: | 2022 |
| المجموعة: | ARPI - Archivio della Ricerca dell'Università di Pisa |
| مصطلحات موضوعية: | chiroptical propertie, circularly polarized luminescence, lanthanide, optical sensing |
| الوصف: | In this minireview, we give an overview on the use of the chiral molecule trans-1,2-diaminocyclohexane (DACH) in several fields of application. This chiral backbone is present in a variety of metal complexes which are employed in (enantioselective) catalysis, chiral discrimination, molecular recognition and supramolecular chemistry. Metal extraction and biochemical and pharmaceutical applications also use the DACH molecule. This contribution is particularly focused on the interesting chemical-physical properties discussed so far in the literature concerning lanthanide-based complexes containing chiral ligands characterized by the presence of DACH in the structure. In particular, the interconnection between luminescence (total and circularly polarized), structure and thermodynamics of Eu(III), Tb(III) and Sm(III) complexes will be discussed also in light of their use as optical or chiroptical probes for the sensing of important analytes dissolved in aprotic and protic polar solvents. Several complexes show potential interest in the solid state as phosphors for light emitting devices or for the detection of volatile organic compounds. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | ELETTRONICO |
| اللغة: | English |
| Relation: | info:eu-repo/semantics/altIdentifier/wos/WOS:000694936400001; volume:6; issue:2; firstpage:1; lastpage:18; numberofpages:18; journal:CHEMPHOTOCHEM; http://hdl.handle.net/11568/1118225; info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85114691540 |
| DOI: | 10.1002/cptc.202100143 |
| الاتاحة: | http://hdl.handle.net/11568/1118225 https://doi.org/10.1002/cptc.202100143 https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cptc.202100143 |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.4D06A611 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/cptc.202100143 |
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