Academic Journal

MoS 2 /Au/Ag Nanostructures for Ratiometric Surface-Enhanced Raman Scattering Determination of Pesticide Residues

التفاصيل البيبلوغرافية
العنوان: MoS 2 /Au/Ag Nanostructures for Ratiometric Surface-Enhanced Raman Scattering Determination of Pesticide Residues
المؤلفون: Xingxing Yu (1738480), Yan Sun (22436), Jieyu Hu (461258), Junjie Wang (172690), Xiumei Zhuang (8384988), Shenghao Zhang (11482903), Haiting Ren (12901424), Hongxing Qiu (12515567), Yueshou Zhang (12901427), Yongjun Hu (1757575)
سنة النشر: 2022
مصطلحات موضوعية: Medicine, Biotechnology, Cancer, Space Science, Chemical Sciences not elsewhere classified, noble metal nanoparticles, enhanced raman scattering, prepared sers substrates, enhancement sers substrates, concentration pesticide residues, showed high sensitivity, internal standard molecules, 2 , pesticide residues surface, ag nanostructures integrate, ratiometric sers analysis, pesticide residues, internal standard, ratiometric surface, ratiometric analysis, raman intensity, plasmonic nanoparticles, ag nanostructures, ag nanostructure, sers detection, successfully detected, promising method, practical applications, logarithmic concentrations, great potential
الوصف: Surface-enhanced Raman scattering (SERS) is a promising method for rapid and sensitive detection of pesticide residues. Herein, a three-dimensional MoS 2 /Au/Ag nanostructure was developed by employing composite systems containing semiconductors, noble metal nanoparticles, and internal standard. The MoS 2 nanoflowers provide abundant anchors for the loading of plasmonic nanoparticles so as to generate intense electromagnetic “hot spots,” and the Au-MBN/Ag nanostructures can increase the accuracy of SERS detection with the calibration ability of the internal standard molecules (4-mercaptobenzonitrile, 4-MBN). Therefore, the MoS 2 /Au/Ag nanostructures integrate the advantages of high-enhancement SERS substrates and high-accuracy ratiometric Raman detection. Moreover, the nanostructures were fabricated via a facile procedure and showed high sensitivity, accuracy, and reproducibility in SERS detection. The nanostructures also showed good linear fitting between the ratios of Raman intensity and logarithmic concentrations of analytes in ratiometric SERS analysis. In addition, thiabendazole (TBZ) in apple juice was successfully detected by using the as-prepared SERS substrates with a limit of detection down to 0.1 ppm in practical applications. To conclude, the MoS 2 /Au/Ag nanostructures showed excellent SERS activity in ratiometric analysis and the substrate is expected to have great potential for the quantitative detection of low-concentration pesticide residues.
نوع الوثيقة: article in journal/newspaper
اللغة: unknown
Relation: https://figshare.com/articles/journal_contribution/MoS_sub_2_sub_Au_Ag_Nanostructures_for_Ratiometric_Surface-Enhanced_Raman_Scattering_Determination_of_Pesticide_Residues/21791457
DOI: 10.1021/acsanm.2c04843.s001
الاتاحة: https://doi.org/10.1021/acsanm.2c04843.s001
Rights: CC BY-NC 4.0
رقم الانضمام: edsbas.4BC0D527
قاعدة البيانات: BASE
الوصف
DOI:10.1021/acsanm.2c04843.s001