التفاصيل البيبلوغرافية
| العنوان: |
In Situ Mechanistic Studies of Two Divergent Synthesis Routes Forming the Heteroanionic BiOCuSe |
| المؤلفون: |
Rebecca McClain (7521959), Christos D. Malliakas (1405939), Jiahong Shen (4338886), Christopher Wolverton (1714792), Mercouri G. Kanatzidis (1350288) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biochemistry, Medicine, Microbiology, Evolutionary Biology, Inorganic Chemistry, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, Bi 3 Se 4, Bi 2 O 2 Se, 3 Cu, anion structure type, Situ Mechanistic Studies, Divergent Synthesis Routes Forming, Cu 2 Se reaction proceeds, synchrotron powder diffraction, 3 Se reaction, intermediate, Bi 2 Se 3, Bi 2 O 3, Cu 2 Se, Heteroanionic BiOCuSe Heteroanionic. |
| الوصف: |
Heteroanionic materials are a burgeoning class of compounds that offer new properties via the targeted selection of anions. However, understanding the design principles and achieving successful syntheses of new materials in this class are in their infancy. To obtain mechanistic insight and a panoramic view of the reaction progression from beginning to end of the formation of a heteroanionic material, we selected BiOCuSe, a well-known thermoelectric compound, and utilized in situ synchrotron powder diffraction as a function of temperature and time. BiOCuSe is a layered material, which crystallizes in a common mixed anion structure type: ZrSiAsFe. Two reactions of starting materials (Bi 2 O 2 Se + Cu 2 Se and Bi 2 O 3 + Bi + 3Cu + 3Se) were studied to determine the effect of precursors on the reaction pathway. Our in situ investigation shows that the ternary–binary Bi 2 O 2 Se + Cu 2 Se reaction proceeds without intermediates to directly form BiOCuSe, while the binary–elemental Bi 2 O 3 + Bi + 3Cu + 3Se reaction generates many intermediates before the final product forms. These intermediates include CuSe, Bi 3 Se 4 , Bi 2 Se 3 , and Cu 2 Se. While the stoichiometric loading of the precursors necessarily dictates the identity of the first intermediates, kinetics also plays a contributing role in stabilizing unexpected intermediates such as CuSe and Bi 3 Se 4 . Understanding and establishing a link between the selection of precursors and the reaction pathways improves the potential for rational synthesis of heteroanionic materials and solid-state reactions in general. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/_i_In_Situ_i_Mechanistic_Studies_of_Two_Divergent_Synthesis_Routes_Forming_the_Heteroanionic_BiOCuSe/15082640 |
| DOI: |
10.1021/jacs.1c03947.s001 |
| الاتاحة: |
https://doi.org/10.1021/jacs.1c03947.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.4B0971D |
| قاعدة البيانات: |
BASE |