Academic Journal
Quantitative NMR Approach to Optimize the Formation of Chemical Building Blocks from Abundant Carbohydrates
| العنوان: | Quantitative NMR Approach to Optimize the Formation of Chemical Building Blocks from Abundant Carbohydrates |
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| المؤلفون: | Elliot, Samuel G., Tolborg, Søren, Sádaba, Irantzu, Taarning, Esben, Meier, Sebastian |
| المساهمون: | Carlsbergfondet |
| المصدر: | ChemSusChem ; volume 10, issue 14, page 2990-2996 ; ISSN 1864-5631 1864-564X |
| بيانات النشر: | Wiley |
| سنة النشر: | 2017 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | The future role of biomass‐derived chemicals relies on the formation of diverse functional monomers in high yields from carbohydrates. Recently, it has become clear that a series of α‐hydroxy acids, esters, and lactones can be formed from carbohydrates in alcohol and water solvents using tin‐containing catalysts such as Sn‐Beta. These compounds are potential building blocks for polyesters bearing additional olefin and alcohol functionalities. An NMR approach was used to identify, quantify, and optimize the formation of these building blocks in the Sn‐Beta‐catalyzed transformation of abundant carbohydrates. Record yields of the target molecules can be achieved by obstructing competing reactions through solvent selection. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/cssc.201700587 |
| الاتاحة: | http://dx.doi.org/10.1002/cssc.201700587 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcssc.201700587 https://onlinelibrary.wiley.com/doi/full/10.1002/cssc.201700587 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.493DDC92 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/cssc.201700587 |
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