التفاصيل البيبلوغرافية
| العنوان: |
Dissociation Dynamics of Anionic Nitrogen Dioxide in the Low-Lying Resonant States |
| المؤلفون: |
Jingchen Xie (14415763), Mengyuan Fan (3814111), Shan Xi Tian (1638478) |
| سنة النشر: |
2023 |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Medicine, Cell Biology, Sociology, Computational Biology, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, Information Systems not elsewhere classified, term puzzling issues, small cross sections, resonant states lead, lying electronic states, anionic nitrogen dioxide, 3 , 2 , 1 , 2 , 1 , sup >–, molecular dissociation threshold, (< sup, indirect dissociation, dissociation dynamics, threshold dissociations, straightened conformation, prompt fragmentation, p )], nuclear motions, multiple degrees |
| الوصف: |
Experimental studies of the dynamics near the molecular dissociation threshold are frequently frustrated, due to the small cross sections and the demand for identification of close-lying electronic states or nuclear motions with multiple degrees of freedom. Using the high-resolution anion velocity map imaging technique, here we report a dynamics study of the dissociations of anionic nitrogen dioxide in low-lying resonant states formed by electron attachment [e – + NO 2 (X 2 A 1 ) → NO 2 – → NO (X 2 Π) + O – ( 2 P)]. The long-term puzzling issues about the near-threshold dissociations of NO 2 – are settled. We suggest that three low-lying resonant states ( 1 B 1 , 3 B 1 , and 3 B 2 ) of NO 2 – contribute to the production of O – at attachment energies of <5 eV. Furthermore, B 1 and B 2 symmetries of the resonant states lead to different anisotropies of the O – angular distribution. At the relatively high electron attachment energies, a prompt fragmentation in the molecular bent conformation competes with an indirect dissociation in the straightened conformation. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Dissociation_Dynamics_of_Anionic_Nitrogen_Dioxide_in_the_Low-Lying_Resonant_States/21887704 |
| DOI: |
10.1021/acs.jpclett.2c03697.s001 |
| الاتاحة: |
https://doi.org/10.1021/acs.jpclett.2c03697.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.44A50A38 |
| قاعدة البيانات: |
BASE |