Academic Journal

Potential of novel porous materials for capture of toluene traces in air under humid conditions

التفاصيل البيبلوغرافية
العنوان: Potential of novel porous materials for capture of toluene traces in air under humid conditions
المؤلفون: Pujol, Quentin, Weber, Guy, Bellat, Jean-Pierre, Grätz, Sven, Krusenbaum, Annika, Borchardt, Lars, Bezverkhyy, Igor
المساهمون: Laboratoire Interdisciplinaire Carnot de Bourgogne (ICB), Université de Technologie de Belfort-Montbeliard (UTBM)-Université de Bourgogne (UB)-Université Bourgogne Franche-Comté COMUE (UBFC)-Centre National de la Recherche Scientifique (CNRS), Ruhr University Bochum = Ruhr-Universität Bochum (RUB)
المصدر: ISSN: 1387-1811.
بيانات النشر: HAL CCSD
Elsevier
سنة النشر: 2022
المجموعة: Université de Bourgogne (UB): HAL
مصطلحات موضوعية: toluene adsorption, BTEX capture, hyper-cross-linked polymers, MOF-derived carbon, [CHIM]Chemical Sciences
الوصف: International audience ; We evaluated the potential of several novel porous materials for toluene capture in air under humid conditions. Four novel porous solids of different nature were studied and compared to two reference materials: two hyper-cross-linked polymers HCP and SMP, the metal organic framework MAF-6 and the activated carbon derived from MAF-6 (AC-MAF-6) with references (Norit RB3 and a dealuminated Y zeolite (DAY)). The affinity of the sorbents for toluene was determined from adsorption isotherms recorded at 25 °C and the low pressure part of the isotherms (< 100 Pa) were successfully fitted with the Unilan equation allowing extrapolation to sub ppm (< 0.1 Pa) concentration range. These equilibrium measurements were complemented by recording the breakthrough curves at 10 Pa of toluene under dry and humid conditions (50 % relative humidity). While MAF-6 and DAY show low dynamic capacities under these conditions, HCP and AC-MAF-6 exhibit much better performances which in the case of AC-MAF-6 are close to RB3 activated carbon even under humid conditions. Moreover, these sorbents can be successfully regenerated under mild conditions (200°C) and show stable performance through adsorption/desorption cycles. Our work suggests that HCP and MAF-6-derived activated carbon are promising materials for toluene capture in air under realistic conditions.
نوع الوثيقة: article in journal/newspaper
اللغة: English
Relation: hal-03844374; https://hal.science/hal-03844374; https://hal.science/hal-03844374/document; https://hal.science/hal-03844374/file/MICMAT-D-22-01434_R2.pdf
DOI: 10.1016/j.micromeso.2022.112204
الاتاحة: https://hal.science/hal-03844374
https://hal.science/hal-03844374/document
https://hal.science/hal-03844374/file/MICMAT-D-22-01434_R2.pdf
https://doi.org/10.1016/j.micromeso.2022.112204
Rights: info:eu-repo/semantics/OpenAccess
رقم الانضمام: edsbas.429BA70D
قاعدة البيانات: BASE
الوصف
DOI:10.1016/j.micromeso.2022.112204