التفاصيل البيبلوغرافية
| العنوان: |
Cross‐Electrophile Coupling between Two Different Tosylates Enabled by Nickel/Palladium Cooperative Catalysis |
| المؤلفون: |
Qu, Ruiling, Zhang, Jinyu, Lian, Zhong |
| المساهمون: |
National Natural Science Foundation of China, Sichuan University |
| المصدر: |
European Journal of Organic Chemistry ; volume 26, issue 40 ; ISSN 1434-193X 1099-0690 |
| بيانات النشر: |
Wiley |
| سنة النشر: |
2023 |
| المجموعة: |
Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: |
Cross‐electrophile coupling reactions are efficient for the construction of carbon‐carbon bonds under relatively mild conditions, and hence widely used for making new molecules. Among various electrophiles, the cross‐electrophile coupling reaction between two different tosylates has been rarely studied. Herein, we present a cross‐electrophile coupling of gem ‐difluoroalkenyl tosylate (C(sp 2 )−OTs) and α‐CF 3 benzyl tosylate (C(sp 3 )−OTs) by nickel/palladium cooperative catalysis. Mechanistic investigation indicated that the activation of C(sp 2 )−OTs bond and C(sp 3 )−OTs bond was facilitated by nickel and palladium respectively. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1002/ejoc.202300874 |
| الاتاحة: |
http://dx.doi.org/10.1002/ejoc.202300874 |
| Rights: |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: |
edsbas.374F1DC6 |
| قاعدة البيانات: |
BASE |