التفاصيل البيبلوغرافية
| العنوان: |
Multiplet effects in the Ru L-2,L-3 x-ray-absorption spectra of Ru(IV) and Ru(V) compounds |
| المؤلفون: |
Hu, Z, von Lips, H, Golden, MS, Fink, J, Kaindl, G, de Groot, FMF, Ebbinghaus, S, Reller, A |
| المساهمون: |
Sub Inorganic Chemistry and Catalysis, Inorganic Chemistry and Catalysis |
| سنة النشر: |
2000 |
| مصطلحات موضوعية: |
TRANSITION-METAL COMPOUNDS, LAYERED PEROVSKITE, SR2RUO4, RU(NH3)6CL3, EDGES, Taverne |
| الوصف: |
We report combined experimental and theoretical investigations of x-ray absorption at the Ru-L-2,L-3 and O-K thresholds of the Ru(IV) compounds RuO2 and Sr2RuO4 and of the Ru(V) compound Sr4Ru2O9 Significant differences in the intensity distribution of the t(2g)-related and e(g)-related peaks between the L-3 and the L-2 edges are found, due to the combined effects of 4d spin-orbit coupling and the interelectronic Coulomb interaction described by the Slater integrals. The observed spectral features can be well reproduced by crystal-field-multiplet calculations. With increasing the Ru valence from TV to V, the spectra are shifted by congruent to 1.5 eV to higher energy at the Ru-L-2,L-3 edges and congruent to 1.0 eV to lower energy at the O-K edge, which is of the same order of magnitude as on going from the divalent to the trivalent late 3d transition-metal oxides. |
| نوع الوثيقة: |
article in journal/newspaper |
| وصف الملف: |
image/pdf |
| اللغة: |
English |
| تدمد: |
1098-0121 |
| Relation: |
https://dspace.library.uu.nl/handle/1874/386349 |
| الاتاحة: |
https://dspace.library.uu.nl/handle/1874/386349 |
| Rights: |
info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: |
edsbas.2EA18B3E |
| قاعدة البيانات: |
BASE |