Academic Journal

Expanded K0.37Fe0.04Al0.07Mn0.89O2 Layered Material as a High-Performance Cathode in Sodium-Ion Batteries

التفاصيل البيبلوغرافية
العنوان: Expanded K0.37Fe0.04Al0.07Mn0.89O2 Layered Material as a High-Performance Cathode in Sodium-Ion Batteries
المؤلفون: Pan Ning, Xinbin Mao, Li Zhou, Hongrui Wang, Feng Zhang, Congshan Zhou, Bei Long, Yuping Wu, Xiongwei Wu
المصدر: Energies; Volume 15; Issue 15; Pages: 5659
بيانات النشر: Multidisciplinary Digital Publishing Institute
سنة النشر: 2022
المجموعة: MDPI Open Access Publishing
مصطلحات موضوعية: layered K 0.37 Fe 0.04 Al 0.07 Mn 0.89 O 2 cathode, expanded interlayer spacing, good structural stability, sol–gel method, sodium-ion batteries
الوصف: Due to a high operating voltage and theoretical capacity, P2-type layered Mn-based metal oxides are considered to be promising cathodes in sodium-ion batteries, but their poor structural stability in the process of Na+ insertion/deinsertion severely hinders their practical application. Here, an interesting K+ pre-intercalation is used to expand the interlayer distance and enhance the electrochemical reversibility of KsFexAlyMnzO2. With a suitable K+ content, the optimized electrode shows a high specific capacity of 135 mAh g−1 at 0.1 C, a good rate capability of 80 mAh g−1 at 5 C and an excellent cycling performance of 76.4% capacity retention after 200 cycles at a high rate of 5 C. This work proves the feasibility of a K+ pre-intercalation strategy in a P2-type layered cathode.
نوع الوثيقة: text
وصف الملف: application/pdf
اللغة: English
Relation: https://dx.doi.org/10.3390/en15155659
DOI: 10.3390/en15155659
الاتاحة: https://doi.org/10.3390/en15155659
Rights: https://creativecommons.org/licenses/by/4.0/
رقم الانضمام: edsbas.2E6C840A
قاعدة البيانات: BASE