Academic Journal
A Novel Application of [Cr(en)2]2+ in the Synthesis of 1,2-Diols from Aromatic Aldehydes
| العنوان: | A Novel Application of [Cr(en)2]2+ in the Synthesis of 1,2-Diols from Aromatic Aldehydes |
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| المؤلفون: | Avila-Sorrosa, Alcives, Vega-Ramírez, Leticia, Rodríguez-Domínguez, Rafael, Salgado-Zamora, Héctor, Peralta-Cruz, Javier, Reyes-Arellano, Alicia |
| المصدر: | Chemistry Letters ; volume 39, issue 5, page 500-501 ; ISSN 0366-7022 1348-0715 |
| بيانات النشر: | Oxford University Press (OUP) |
| سنة النشر: | 2010 |
| مصطلحات موضوعية: | General Chemistry |
| الوصف: | A reductive pinacol type arylaldehyde homocoupling process mediated by the [Cr(en)2]2+ complex is described. This procedure affords the meso-stereoisomer as the major product, an unexpected result considering that most organometallic methodologies preferentially yield the dl-isomer. Additionally, the method represents a novel application of the [Cr(en)2]2+. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1246/cl.2010.500 |
| الاتاحة: | http://dx.doi.org/10.1246/cl.2010.500 https://academic.oup.com/chemlett/article-pdf/39/5/500/55602308/cl.2010.500.pdf |
| Rights: | https://academic.oup.com/pages/standard-publication-reuse-rights |
| رقم الانضمام: | edsbas.2BEE7556 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1246/cl.2010.500 |
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