Academic Journal
Self-Assembly and Gelation Study of Dipeptide Isomers with Norvaline and Phenylalanine
| العنوان: | Self-Assembly and Gelation Study of Dipeptide Isomers with Norvaline and Phenylalanine |
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| المؤلفون: | Scarel E., Pierri G., Rozhin P., Adorinni S., Polentarutti M., Tedesco C., Marchesan S. |
| المساهمون: | Scarel, E., Pierri, G., Rozhin, P., Adorinni, S., Polentarutti, M., Tedesco, C., Marchesan, S. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | self-assembly, gel, crystal, XRD, supramolecular chemistry, norvaline, phenylalanine, chirality, D-amino acid, peptides |
| الوصف: | Dipeptides have emerged as attractive building blocks for supramolecular materials thanks to their low-cost, inherent biocompatibility, ease of preparation, and environmental friendliness as they do not persist in the environment. In particular, hydrophobic amino acids are ideal candidates for self-assembly in polar and green solvents, as a certain level of hydrophobicity is required to favor their aggregation and reduce the peptide solubility. In this work, we analyzed the ability to self-assemble and the gel of dipeptides based on the amino acids norvaline (Nva) and phenylalanine (Phe), studying all their combinations and not yielding to enantiomers, which display the same physicochemical properties, and hence the same self-assembly behavior in achiral environments as those studied herein. A single-crystal X-ray diffraction of all the compounds revealed fine details over their molecular packing and non-covalent interactions. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | info:eu-repo/semantics/altIdentifier/wos/WOS:000900536000001; volume:4; firstpage:1417; lastpage:1428; numberofpages:12; journal:CHEMISTRY; https://hdl.handle.net/11386/4821753; info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85147823201; https://www.mdpi.com/2624-8549/4/4/93 |
| DOI: | 10.3390/chemistry4040093 |
| الاتاحة: | https://hdl.handle.net/11386/4821753 https://doi.org/10.3390/chemistry4040093 https://www.mdpi.com/2624-8549/4/4/93 |
| رقم الانضمام: | edsbas.2A27660E |
| قاعدة البيانات: | BASE |
| DOI: | 10.3390/chemistry4040093 |
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