التفاصيل البيبلوغرافية
| العنوان: |
Stereoselective Dehydroxyboration of Allylic Alcohols to Access ( E )‑Allylboronates by a Combination of C–OH Cleavage and Boron Transfer under Iron Catalysis |
| المؤلفون: |
Wei Su (89824), Ting-Ting Wang (211146), Xia Tian (142861), Jian-Rong Han (9444342), Xiao-Li Zhen (9444339), Shi-Ming Fan (9444345), Ya-Xin You (11708175), Yu-Kun Zhang (6598976), Rui-Xiao Qiao (9444336), Qiushi Cheng (9444348), Shouxin Liu (2001382) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biochemistry, Genetics, Physiology, Pharmacology, Biotechnology, Ecology, Immunology, Developmental Biology, Marine Biology, Inorganic Chemistry, Hematology, Infectious Diseases, Chemical Sciences not elsewhere classified, underwent smooth transformation, key component involved, iron catalysis iron, 2 ′ dehydroxyboration, >)- stereoselective allylboronates, n , stereoselective dehydroxyboration, e <, >)‑ allylboronates, natural products, functional groups, especially derived, diverse structures, catalyzed direct, boron group, allylic alcohols, access (< |
| الوصف: |
Iron-catalyzed direct S N 2′ dehydroxyboration of allylic alcohols has been developed to access ( E )-stereoselective allylboronates. Allylic alcohols with diverse structures and functional groups, especially derived from natural products, underwent smooth transformation. The six-membered ring transition state formed by allylic alcohols and iron–boron intermediate was indicated to be the key component involved in transfer of the boron group, activation of the C–OH bond, and control of the stereoselectivity. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Stereoselective_Dehydroxyboration_of_Allylic_Alcohols_to_Access_i_E_i_Allylboronates_by_a_Combination_of_C_OH_Cleavage_and_Boron_Transfer_under_Iron_Catalysis/17018481 |
| DOI: |
10.1021/acs.orglett.1c03359.s001 |
| الاتاحة: |
https://doi.org/10.1021/acs.orglett.1c03359.s001 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.29B4AFD5 |
| قاعدة البيانات: |
BASE |