Academic Journal

Factors influencing the bioavailability of some selected elements in the agricultural soil of a geologically varied territory: The Campania region (Italy) case study ; Geoderma

التفاصيل البيبلوغرافية
العنوان: Factors influencing the bioavailability of some selected elements in the agricultural soil of a geologically varied territory: The Campania region (Italy) case study ; Geoderma
المؤلفون: Guarino, Annalise, Albanese, Stefano, Cicchella, Domenico, Ebrahimi, Pooria, Dominech, Salvatore, Pacifico, Lucia Rita, Rofrano, Giuseppe, Nicodemo, Federico, Pizzolante, Antonio, Allocca, Carolina, Romano, Nunzio, De Vivo, Benedetto, Lima, Annamaria
بيانات النشر: Elsevier
سنة النشر: 2022
المجموعة: VTechWorks (VirginiaTech)
مصطلحات موضوعية: Ammonium nitrate, Aqua Regia, Bioavailability, Geochemical mapping, Regression analysis
جغرافية الموضوع: Italy
الوصف: Bioavailability of some major and trace elements was evaluated in 1,993 topsoil samples collected across Campania region (Southern Italy). A main focus was made on Al, Ca, K, Mg, Cu, Tl since they are linked, for different reasons, to agriculture. Bioavailability was assessed by an extraction with ammonium nitrate and the data were compared with the pseudo-total concentration determined by Aqua Regia digestion. Geochemical maps of the pseudo-total and bioavailable concentrations were generated using a multifractal inverse distance weighted (MIDW) interpolation. In addition, the spatial distribution patterns of the percent bioavailability of elements, based on the ratio among bioavailable and the pseudo-total fractions, were also determined. The median value of the percent bioavailability showed the order Ca > K >> Mg. Tl >> Cu >> Al and it represents a positive finding in terms of both agricultural productivity and environmental quality. Further, a multiple linear regression was finally applied to data to unveil any dependence of the bioavailable fraction on the pseudo-total content of elements. The grain size distribution and organic matter content of samples were later included to evaluate their possible role in promoting the environmental availability of elements. The pseudo-total concentrations of Al, Ca, K, and Mg alone resulted to be poorly able to predict the variability of the bioavailable fraction. The addition of the grain size distribution and organic matter content to the models expanded the predictive capability of Ca, K, and Mg whereas a marginal improvement was showed by Al, Cu, and Tl. This study represents a methodological contribution to a better understanding of the processes underlying the spatial variability of chemical elements in soil. Considering the positive outcomes obtained, further researches were planned to include more variables (e.g. soil pH, redox potential, content in Iron and Manganese oxides, etc.) in the predictive models. ; Istituto Zooprofilattico ...
نوع الوثيقة: article in journal/newspaper
وصف الملف: application/pdf
اللغة: English
تدمد: 1872-6259
Relation: 116207; http://hdl.handle.net/10919/114498; https://doi.org/10.1016/j.geoderma.2022.116207; 428
DOI: 10.1016/j.geoderma.2022.116207
الاتاحة: http://hdl.handle.net/10919/114498
https://doi.org/10.1016/j.geoderma.2022.116207
Rights: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International ; http://creativecommons.org/licenses/by-nc-nd/4.0/
رقم الانضمام: edsbas.26C1E18
قاعدة البيانات: BASE
الوصف
تدمد:18726259
DOI:10.1016/j.geoderma.2022.116207