التفاصيل البيبلوغرافية
| العنوان: |
Tuning Nanoparticle Surface Chemistry and Interfacial Properties for Highly Stable Nitrogen-In-Brine Foams |
| المؤلفون: |
Shehab Alzobaidi (1442098), Chang Da (1442113), Pingkeng Wu (2013625), Xuan Zhang (56049), Nava J. Rabat-Torki (10680424), Justin M. Harris (10680427), Jamie E. Hackbarth (10680430), Congwen Lu (10680433), Dongdong Hu (1524601), Keith P. Johnston (1294929) |
| سنة النشر: |
2021 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Biophysics, Biochemistry, Ecology, Inorganic Chemistry, Hematology, Virology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, 48 h, foam bubble size, NP adsorption, 20 nm silica NPs, CO 2 sequestration, Tuning Nanoparticle Surface Chemistry, Stable Nitrogen-In-Brine Foams, surface chemistries, divalent ions, design NP-laden, dilational elasticity arrests coars., interface, Interfacial Properties, oil recovery, CaCl 2 concentrations, divalent ion concentrations, foam applications |
| الوصف: |
The design of surface chemistries on nanoparticles (NPs) to stabilize gas/brine foams with concentrated electrolytes, especially with divalent ions, has been elusive. Herein, we tune the surface of 20 nm silica NPs by grafting a hydrophilic and a hydrophobic ligand to achieve two seemingly contradictory goals of colloidal stability in brine and high NP adsorption to yield a viscoelastic gas–brine interface. Highly stable nitrogen/water (N 2 /brine) foams are formed with CaCl 2 concentrations up to 2% from 25 to 90 °C. The viscoelastic gas–brine interface retards drainage of the lamellae, and the high dilational elasticity arrests coarsening (Ostwald ripening) with no observable change in foam bubble size over 48 h. The ability to design NP-laden viscoelastic interfaces for highly stable foams, even with high divalent ion concentrations, is of fundamental mechanistic interest for a broad range of foam applications and in particular foams for CO 2 sequestration and enhanced oil recovery. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://figshare.com/articles/journal_contribution/Tuning_Nanoparticle_Surface_Chemistry_and_Interfacial_Properties_for_Highly_Stable_Nitrogen-In-Brine_Foams/14459560 |
| DOI: |
10.1021/acs.langmuir.1c00832.s002 |
| الاتاحة: |
https://doi.org/10.1021/acs.langmuir.1c00832.s002 |
| Rights: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.26B741D4 |
| قاعدة البيانات: |
BASE |