Academic Journal

Effect of a Magnetic Field on the Electrode Process of Al Electrodeposition in a [Emim]Cl-AlCl 3 Ionic Liquid

التفاصيل البيبلوغرافية
العنوان: Effect of a Magnetic Field on the Electrode Process of Al Electrodeposition in a [Emim]Cl-AlCl 3 Ionic Liquid
المؤلفون: Jinxia Wang (355966), Xiangyue Liu (7062335), Hongwei Xie (39967), Huayi Yin (2106763), Qiushi Song (8162034), Zhiqiang Ning (2030629)
سنة النشر: 1753
المجموعة: Smithsonian Institution: Digital Repository
مصطلحات موضوعية: Biochemistry, Physiology, Biotechnology, Science Policy, Plant Biology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, electric double layer, electrochemical impedance spectroscopy, cu electrode plane, 3 , 2 , perpendicular magnetic field, ionic liquid composed, electrodeposited aluminum layer, constant current density, emim ]­ cl, magnetic field, ionic liquid, electrode process, electrochemical reduction, zero charge, usually used, solution electrolyte, results indicated, pure ions, mass transport, different capacitances, cyclic voltammetry
الوصف: The magnetohydrodynamic (MHD) effect was usually used to improve the mass transport during electrodeposition in a solution electrolyte. Herein, we reported the effect of a magnetic field on the electrode process of Al electrodeposition in a [Emim]­Cl-AlCl 3 ionic liquid composed of pure ions. Under a uniform and perpendicular magnetic field to the Cu electrode plane, electrochemical impedance spectroscopy (EIS) of the circuit, the cyclic voltammetry (CV) curves, and the different capacitances at the potential of zero charge (PZC) were measured, and the electrodeposition of aluminum was carried out at a constant current density. The results indicated that a vertical magnetic field significantly reduced the resistance (activation energy) for charge transfer of electrochemical reduction of Al 2 Cl 7 – ; meanwhile, the capacitance of an electric double layer (EDL) and the density of the electrodeposited aluminum layer were increased.
نوع الوثيقة: article in journal/newspaper
اللغة: unknown
Relation: https://figshare.com/articles/journal_contribution/Effect_of_a_Magnetic_Field_on_the_Electrode_Process_of_Al_Electrodeposition_in_a_Emim_Cl-AlCl_sub_3_sub_Ionic_Liquid/17174362
DOI: 10.1021/acs.jpcb.1c05410.s001
الاتاحة: https://doi.org/10.1021/acs.jpcb.1c05410.s001
Rights: CC BY-NC 4.0
رقم الانضمام: edsbas.25BB5CD9
قاعدة البيانات: BASE
الوصف
DOI:10.1021/acs.jpcb.1c05410.s001