Academic Journal
APPLICATION OF TOTAL-REFLECTION X-RAY FLUORESCENCE SPECTROMETRY (TXRF) TO GEOLOGICAL OBJECTS: EXPERIENCE OF THE TXRF LABORATORY, CENTER FOR GEODYNAMICS AND GEOCHRONOLOGY ; ПРИМЕНЕНИЕ МЕТОДА РЕНТГЕНОФЛУОРЕСЦЕНТНОЙ СПЕКТРОМЕТРИИ С ПОЛНЫМ ВНЕШНИМ ОТРАЖЕНИЕМ (TXRF) К ГЕОЛОГИЧЕСКИМ ОБЪЕКТАМ: ОПЫТ ЛАБОРАТОРИИ TXRF (ЦКП «ГЕОДИНАМИКА И ГЕОХРОНОЛОГИЯ»)
| العنوان: | APPLICATION OF TOTAL-REFLECTION X-RAY FLUORESCENCE SPECTROMETRY (TXRF) TO GEOLOGICAL OBJECTS: EXPERIENCE OF THE TXRF LABORATORY, CENTER FOR GEODYNAMICS AND GEOCHRONOLOGY ; ПРИМЕНЕНИЕ МЕТОДА РЕНТГЕНОФЛУОРЕСЦЕНТНОЙ СПЕКТРОМЕТРИИ С ПОЛНЫМ ВНЕШНИМ ОТРАЖЕНИЕМ (TXRF) К ГЕОЛОГИЧЕСКИМ ОБЪЕКТАМ: ОПЫТ ЛАБОРАТОРИИ TXRF (ЦКП «ГЕОДИНАМИКА И ГЕОХРОНОЛОГИЯ») |
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| المؤلفون: | A. S. Maltsev, G. V. Pashkova, А. С. Мальцев, Г. В. Пашкова |
| المساهمون: | The research was performed using the equipment of the Centre for Geodynamics and Geochronology of the Institute of the Earth’s Crust SB RAS (grant 075-15-2021-682), Исследования выполнены на оборудовании Центра коллективного пользования «Геодинамика и геохронология» Института земной коры СО РАН (грант № 075-15-2021-682) |
| المصدر: | Geodynamics & Tectonophysics; Том 13, № 2 (2022); 0601 ; Геодинамика и тектонофизика; Том 13, № 2 (2022); 0601 ; 2078-502X |
| بيانات النشر: | Institute of the Earth's crust of the Russian Academy of Sciences, Siberian Branch |
| سنة النشر: | 2022 |
| المجموعة: | Geodynamics & Tectonophysics (E-Journal) / Геодинамика и тектонофизика |
| مصطلحات موضوعية: | осадки, multi-elemental analysis, sample preparation, accuracy assessment, apatite, ores, nodules, ceramics, sediments, многоэлементный анализ, пробоподготовка, оценка точности, апатит, руды, конкреции, керамика |
| الوصف: | Unlike conventional X-ray fluorescence spectrometry, the total-reflection X-ray fluorescence spectrometry is not a widespread and routine method for analyzing solid samples with mineral matrix, but it has a great potential for geochemical, geological, and archaeological studies. Rapid multi-elemental analysis of very small sample amounts can be performed by the internal standard method which does not require the matrix-matched reference materials. This is an undoubted advantage of the TXRF method over the conventional X-ray fluorescence method, especially if there is a limited available sample amount and a lack of well-characterized reference materials. This paper presents our experience with the application of TXRF spectrometry in the elemental analysis of apatite, ceramics, sediments, ores, and nodules. Special attention has been paid to the sample preparation procedure because it is one of the main sources of errors in the analysis. Preparing thin homogeneous specimen from the solid sample with a complex mineral matrix is not easy. Sample preparation strategy should be chosen considering the features of an analytical object, the content of the elements to be determined, and the accuracy required for a reliable interpretation. Consideration is being given to the examples of the preparation of a suspension for rapid analysis of ores and sediments, and to the original techniques of chemical decomposition for apatite and ceramics. ; В отличие от традиционной рентгенофлуоресцентной спектрометрии, рентгенофлуоресцентная спектрометрия с полным внешним отражением не является распространенным и рутинным методом анализа твердых образцов с минеральной матрицей, но имеет большой потенциал для геохимических, геологических и археологических исследований. Быстрый многоэлементный анализ очень малого количества образца может быть выполнен с помощью способа внутреннего стандарта, который не требует стандартных образцов для калибровки. Это несомненное преимущество метода TXRF по сравнению с традиционным рентгенофлуоресцентным ... |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | Russian |
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| DOI: | 10.5800/GT-2022-13-2s-0601 |
| الاتاحة: | https://www.gt-crust.ru/jour/article/view/1437 https://doi.org/10.5800/GT-2022-13-2s-0601 |
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| رقم الانضمام: | edsbas.24251509 |
| قاعدة البيانات: | BASE |
| DOI: | 10.5800/GT-2022-13-2s-0601 |
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