Academic Journal
Probing the reactive intermediate species generated during electrocatalysis by scanning electrochemical microscopy
| العنوان: | Probing the reactive intermediate species generated during electrocatalysis by scanning electrochemical microscopy |
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| المؤلفون: | Noël, Jean-Marc, Kanoufi, Frédéric |
| المساهمون: | Interfaces, Traitements, Organisation et Dynamique des Systèmes (ITODYS (UMR_7086)), Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité), Université Paris Cité (UPCité), ANR-20-CE42-0001,PIRaNa,Imagerie quantitative de la production de radicaux hydroxyles à proximité de nano-objets individuels: une méthodologie opto-electrochimique(2020) |
| المصدر: | ISSN: 2451-9103. |
| بيانات النشر: | HAL CCSD Elsevier |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Scanning electrochemical microscopy, reactive intermediate species, nanoelectrochemistry, numerical simulation, [CHIM]Chemical Sciences |
| الوصف: | International audience ; Reactive intermediate species (RIS) are of major importance in many chemical and biological reactions. Due to the high reactivity their presence are usually confined at the place of their formation. Whereas electrochemical tools can electrogenerate them through various mechanistic paths, the local electrochemical probes, such as a micro/nanoelectrode tip of the scanning electrochemical microscopy (SECM), are by essence well adapted to catch their formation and reactivity at the location of their production. This review presents the recent local electrochemical probe strategies employed to probe RIS down to the nanometer scale, either immobilized on the surface of an electrode or within a reaction layer, in solution. It is illustrated by examples borrowed from the field of electrocatalysis, with emphasis on the contributions of numerical simulation to derive quantitative information. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | hal-03816543; https://hal.science/hal-03816543; https://hal.science/hal-03816543/document; https://hal.science/hal-03816543/file/MS_Current%20Opinion%20in%20Electrochemistry_HAL.pdf |
| DOI: | 10.1016/j.coelec.2022.101071 |
| الاتاحة: | https://hal.science/hal-03816543 https://hal.science/hal-03816543/document https://hal.science/hal-03816543/file/MS_Current%20Opinion%20in%20Electrochemistry_HAL.pdf https://doi.org/10.1016/j.coelec.2022.101071 |
| Rights: | info:eu-repo/semantics/OpenAccess |
| رقم الانضمام: | edsbas.23DCCD34 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1016/j.coelec.2022.101071 |
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