Academic Journal
β-Functionalization of 4a-aza-8a-boranaphthalene via Iridium-catalyzed C-H Borylation
| العنوان: | β-Functionalization of 4a-aza-8a-boranaphthalene via Iridium-catalyzed C-H Borylation |
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| المؤلفون: | Valencia Nieto, Isabel, Sucunza Sáenz, David, Mendicuti Madrid, Francisco Enrique Javier, García García, Patricia, Vaquero López, Juan José |
| المساهمون: | Universidad de Alcalá. Departamento de Química Analítica, Química Física e Ingeniería Química, Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica, Unidad docente Química Orgánica |
| سنة النشر: | 2023 |
| المجموعة: | e_Buah - Biblioteca Digital de la Universidad de Alcalá |
| مصطلحات موضوعية: | BN-naphthalene, C-H activation, iridiumcross-coupling, catalysis, Química, Chemistry |
| الوصف: | A general method for the functionalization of 4a-aza-8a-boranaphthalene in the position ? to the nitrogen atom has been developed. This method is based on a regioselective iridium-catalyzed C?H activation process for the introduction of a boronate group, which can subsequently be transformed into a variety of aryl or alkynyl groups via cross-coupling reactions. Selective mono- or difunctionalization can be achieved by controlling the reaction conditions during the borylation step. The photophysical properties of the obtained 3- or 3,6-substituted BN-naphthalenes have been evaluated, and some of them have been found to be significantly fluorescent, with fluorescence quantum yields up to 0.85. ; Ministerio de Ciencia e Innovación ; Instituto de Salud Carlos III |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| Relation: | info:eu-repo/grantAgreement/MICINN//PID2020-115128RB-I00/ES/; info:eu-repo/grantAgreement/MICINN//PID2021-1242470B-C21/ES/; info:eu-repo/grantAgreement/MICINN//PID2020-118384GB-I00/ES/; info:eu-repo/grantAgreement/ISCIII//ISCIIIRICORS2040%2FRD21%2F0005%2F0005/ES/; http://hdl.handle.net/10017/59187; AR/0000044491; Advanced Synthesis and Catalysis; 365; 2552; 15; 2545 |
| DOI: | 10.1002/adsc.202300408 |
| الاتاحة: | http://hdl.handle.net/10017/59187 https://doi.org/10.1002/adsc.202300408 |
| Rights: | © The Authors ; Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) ; http://creativecommons.org/licenses/by-nc-nd/4.0/ ; info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.22756A5C |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/adsc.202300408 |
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