Academic Journal
Dinuclear Nickel Complexes Doubly Bridged by Hydrogencyanamido Ligands: Synthesis, Structures and Magnetic Properties
| العنوان: | Dinuclear Nickel Complexes Doubly Bridged by Hydrogencyanamido Ligands: Synthesis, Structures and Magnetic Properties |
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| المؤلفون: | Kuwabara, Takuya, Shiga, Natsumi, Kodama, Shintaro, Sato, Hirohiko, Houjou, Hirohiko, Ishii, Youichi |
| المصدر: | European Journal of Inorganic Chemistry ; volume 2018, issue 29, page 3413-3417 ; ISSN 1434-1948 1099-0682 |
| بيانات النشر: | Wiley |
| سنة النشر: | 2018 |
| المجموعة: | Wiley Online Library (Open Access Articles via Crossref) |
| الوصف: | Novel dinuclear nickel complexes bridged by two hydrogencyanamido (NCNH – ) ligands [(NiL) 2 (µ 2 ‐NHCN‐ N , N′ ) 2 ] 2+ have been synthesized and structurally characterized. X‐ray diffraction analysis suggests that each hydrogencyanamido ligand coordinates as a cyanamide anion (N≡C–NH – ) rather than a carbodiimide anion (N + =C=NH – ). The structure of the central (NiNCN) 2 ring skeleton varies slightly depending on the ancillary ligands, which affects strength of the Ni ··· Ni antiferromagnetic coupling judging from the SQUID measurements. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1002/ejic.201800457 |
| الاتاحة: | http://dx.doi.org/10.1002/ejic.201800457 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejic.201800457 https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201800457 https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ejic.201800457 |
| Rights: | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| رقم الانضمام: | edsbas.21789824 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/ejic.201800457 |
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