التفاصيل البيبلوغرافية
| العنوان: |
Bifunctional Pd‑O x Center at the Liquid–Solid–Gas Triphase Interface for H 2 O 2 Photosynthesis |
| المؤلفون: |
Minghui Sun, Xiaoguang Wang, Yi Li, Honghui Pan, Muthu Murugananthan, Yidong Han, Jie Wu, Ming Zhang, Yanrong Zhang, Zhenhui Kang |
| سنة النشر: |
2022 |
| مصطلحات موضوعية: |
Medicine, Space Science, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, inhibit side reactions, containing ligands combined, 9 μmol g, relatively separated catalyst, photoelectronic dual center, holy grail reaction, bifunctional pd ‑, 4 , 2 , x <, dynamic catalyst, sub ><, visible illumination, tunable via, superhydrophobic photocatalyst, solar energy, research opens, reaction intermediates, pure water, photosynthetic yield, manufacturing route, intriguing avenue, socio |
| الوصف: |
The coupling of H 2 O and O 2 by solar energy is regarded as the Holy Grail reaction for a manufacturing route of H 2 O 2 ; however, its efficiency has suffered from low O 2 solubility in aqueous solution and difficult-to-inhibit side reactions. Herein, a liquid–solid–gas triphase system has been designed to directly utilize abundant atmospheric O 2 for H 2 O 2 photosynthesis, the most important of which is the superhydrophobic photocatalyst of amino-containing ligands combined with Pd, loaded on BiVO 4 (Pd/A/BiVO 4 ). This relatively separated catalyst and product system successfully avoids the decomposition of produced H 2 O 2 and contributes to the accumulation of a high-concentration H 2 O 2 solution. The enrichment of O 2 and the kinetics of carriers and reaction intermediates are tunable via the interaction between Pd and amino groups, which promotes the photosynthetic yield of H 2 O 2 to 805.9 μmol g –1 h –1 in pure water under visible illumination. During the reaction, O 2 is not only converted into H 2 O 2 as a reactant but also participates in the construction of Pd-O x sites as a dynamic catalyst. Also, the Pd-O x intermediate is identified as a catalytic and photoelectronic dual center. This research opens up an intriguing avenue for designing the H 2 O 2 photosynthesis system. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| Relation: |
https://doi.org/10.1021/acscatal.1c05324.s001 |
| DOI: |
10.1021/acscatal.1c05324.s001 |
| الاتاحة: |
https://doi.org/10.1021/acscatal.1c05324.s001 |
| Rights: |
undefined |
| رقم الانضمام: |
edsbas.1E3E4F51 |
| قاعدة البيانات: |
BASE |