Academic Journal
Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework
| العنوان: | Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework |
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| المؤلفون: | Núñez-López, Alejandro, Galbiati, Marta, Padial, Natalia M., Ganivet, Carolina R., Tatay Aguilar, Sergio, Pardo Marín, Emilio, Armentano, Donatella, Martí Gastaldo, Carlos |
| المصدر: | Núñez-López, Alejandro Galbiati, Marta Padial, Natalia M. Ganivet, Carolina R. Tatay Aguilar, Sergio Pardo Marín, Emilio Armentano, Donatella Martí Gastaldo, Carlos 2019 Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework Angewandte Chemie 58 27 9179 9183 |
| سنة النشر: | 2019 |
| المجموعة: | Universitat de València: Roderic - Repositorio de contenido libre |
| مصطلحات موضوعية: | Química organometàl·lica, Reactivitat (Química) |
| الوصف: | Metal-organic frameworks can be used as porous templates to exert control over polymerization reactions. Shown here are the possibilities offered by these crystalline, porous nanoreactors to capture highly‐reactive intermediates for a better understanding of the mechanism of polymerization reactions. By using a cyclodextrin framework the polymerization of pyrrole is restricted, capturing the formation of terpyrrole cationic intermediates. Single‐crystal X‐ray diffraction is used to provide definite information on the supramolecular interactions that induce the formation and stabilization of a conductive array of cationic complexes. |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | Angewandte Chemie, 2019, vol. 58, num. 27, p. 9179-9183; https://hdl.handle.net/10550/70758; https://doi.org/10.1002/anie.201904890; 133389 |
| DOI: | 10.1002/anie.201904890 |
| الاتاحة: | https://hdl.handle.net/10550/70758 https://doi.org/10.1002/anie.201904890 |
| Rights: | info:eu-repo/semantics/openAccess |
| رقم الانضمام: | edsbas.1712D982 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1002/anie.201904890 |
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