Academic Journal
Reducing capacity and voltage decay of Co‐free Li1.2Ni0.2Mn0.6O2 as positive electrode material for lithium batteries employing an ionic liquid‐based electrolyte
| العنوان: | Reducing capacity and voltage decay of Co‐free Li1.2Ni0.2Mn0.6O2 as positive electrode material for lithium batteries employing an ionic liquid‐based electrolyte |
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| المؤلفون: | Wu, Fanglin, Kim, Guk‐Tae, Diemant, Thomas, Kuenzel, Matthias, Schür, Annika Regitta, Gao, Xinpei, Qin, Bingsheng, Alwast, Dorothea, Jusys, Zenonas, Behm, Rolf Jürgen, Geiger, Dorin, Kaiser, Ute, Passerini, Stefano |
| بيانات النشر: | Universität Ulm |
| سنة النشر: | 2020 |
| المجموعة: | OPARU (OPen Access Repository of Ulm University) |
| مصطلحات موضوعية: | cobalt‐free cathodes, ionic liquid electrolytes, lithium batteries, lithium‐rich layered oxides, voltage fading, Lithium cells, Lithium-Luft-Akkumulator |
| الوصف: | Lithium-rich layered oxides (LRLOs) exhibit specific capacities above 250 mAh g−1, i.e., higher than any of the commercially employed lithium-ion-positive electrode materials. Such high capacities result in high specific energies, meeting the tough requirements for electric vehicle applications. However, LRLOs generally suffer from severe capacity and voltage fading, originating from undesired structural transformations during cycling. Herein, the eco-friendly, cobalt-free Li1.2Ni0.2Mn0.6O2 (LRNM), offering a specific energy above 800 Wh kg−1 at 0.1 C, is investigated in combination with a lithium metal anode and a room temperature ionic liquid-based electrolyte, i.e., lithium bis(trifluoromethanesulfonyl)imide and N-butyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide. As evidenced by electrochemical performance and high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, and online differential electrochemical mass spectrometry characterization, this electrolyte is capable of suppressing the structural transformation of the positive electrode material, resulting in enhanced cycling stability compared to conventional carbonate-based electrolytes. Practically, the capacity and voltage fading are significantly limited to only 19% and 3% (i.e., lower than 0.2 mV per cycle), respectively, after 500 cycles. Finally, the beneficial effect of the ionic liquid-based electrolyte is validated in lithium-ion cells employing LRNM and Li4Ti5O12. These cells achieve a promising capacity retention of 80% after 500 cycles at 1 C. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| DOI: | 10.18725/OPARU-43201 |
| الاتاحة: | https://doi.org/10.18725/OPARU-43201 http://nbn-resolving.de/urn:nbn:de:bsz:289-oparu-43277-8 |
| رقم الانضمام: | edsbas.1438BE8 |
| قاعدة البيانات: | BASE |
| DOI: | 10.18725/OPARU-43201 |
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