Academic Journal
Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl)Furan over Ru/Co3O4
| العنوان: | Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl)Furan over Ru/Co3O4 |
|---|---|
| المؤلفون: | Ting Wang, Junhua Zhang, Wenxing Xie, Yanjun Tang, Daliang Guo, Yonghao Ni |
| المصدر: | Catalysts; Volume 7; Issue 3; Pages: 92 |
| بيانات النشر: | Multidisciplinary Digital Publishing Institute |
| سنة النشر: | 2017 |
| المجموعة: | MDPI Open Access Publishing |
| مصطلحات موضوعية: | biomass, 5-hydroxymethylfurfural, 2,5-bis-(hydroxymethyl)furan, catalytic transfer hydrogenation, ruthenium based catalyst |
| الوصف: | 2,5-Bis-(hydroxymethyl)furan (BHMF) is an important biomass-based platform chemical that can be derived from the hydrogenation of biomass-based 5-hydroxymethylfurfural (HMF). In this paper, the formation of BHMF from HMF via the catalytic transfer hydrogenation (CTH) process, using isopropanol as the hydrogen source and Ru/Co3O4 as the catalyst, was studied. The results revealed that the Ru/Co3O4 catalyst displayed a high catalytic efficiency, and that a BHMF yield of up to 82% was obtained at 190 °C in 6 h. Moreover, it was found that the recovered Ru/Co3O4 exhibited a similar catalytic activity to the pristine Ru/Co3O4 catalyst. These results supported the conclusion that the present CTH process is an attractive green route for the synthesis of BHMF from biomass-based HMF. |
| نوع الوثيقة: | text |
| وصف الملف: | application/pdf |
| اللغة: | English |
| Relation: | Catalytic Materials; https://dx.doi.org/10.3390/catal7030092 |
| DOI: | 10.3390/catal7030092 |
| الاتاحة: | https://doi.org/10.3390/catal7030092 |
| Rights: | https://creativecommons.org/licenses/by/4.0/ |
| رقم الانضمام: | edsbas.131D824A |
| قاعدة البيانات: | BASE |
| ResultId |
1 |
|---|---|
| Header |
edsbas BASE edsbas.131D824A 871 3 Academic Journal academicJournal 871.106628417969 |
| PLink |
https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&scope=site&db=edsbas&AN=edsbas.131D824A&custid=s6537998&authtype=sso |
| FullText |
Array
(
[Availability] => 0
)
Array ( [0] => Array ( [Url] => https://doi.org/10.3390/catal7030092# [Name] => EDS - BASE [Category] => fullText [Text] => View record in BASE [MouseOverText] => View record in BASE ) ) |
| Items |
Array
(
[Name] => Title
[Label] => Title
[Group] => Ti
[Data] => Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl)Furan over Ru/Co3O4
)
Array ( [Name] => Author [Label] => Authors [Group] => Au [Data] => <searchLink fieldCode="AR" term="%22Ting+Wang%22">Ting Wang</searchLink><br /><searchLink fieldCode="AR" term="%22Junhua+Zhang%22">Junhua Zhang</searchLink><br /><searchLink fieldCode="AR" term="%22Wenxing+Xie%22">Wenxing Xie</searchLink><br /><searchLink fieldCode="AR" term="%22Yanjun+Tang%22">Yanjun Tang</searchLink><br /><searchLink fieldCode="AR" term="%22Daliang+Guo%22">Daliang Guo</searchLink><br /><searchLink fieldCode="AR" term="%22Yonghao+Ni%22">Yonghao Ni</searchLink> ) Array ( [Name] => TitleSource [Label] => Source [Group] => Src [Data] => Catalysts; Volume 7; Issue 3; Pages: 92 ) Array ( [Name] => Publisher [Label] => Publisher Information [Group] => PubInfo [Data] => Multidisciplinary Digital Publishing Institute ) Array ( [Name] => DatePubCY [Label] => Publication Year [Group] => Date [Data] => 2017 ) Array ( [Name] => Subset [Label] => Collection [Group] => HoldingsInfo [Data] => MDPI Open Access Publishing ) Array ( [Name] => Subject [Label] => Subject Terms [Group] => Su [Data] => <searchLink fieldCode="DE" term="%22biomass%22">biomass</searchLink><br /><searchLink fieldCode="DE" term="%225-hydroxymethylfurfural%22">5-hydroxymethylfurfural</searchLink><br /><searchLink fieldCode="DE" term="%222%2C5-bis-%28hydroxymethyl%29furan%22">2,5-bis-(hydroxymethyl)furan</searchLink><br /><searchLink fieldCode="DE" term="%22catalytic+transfer+hydrogenation%22">catalytic transfer hydrogenation</searchLink><br /><searchLink fieldCode="DE" term="%22ruthenium+based+catalyst%22">ruthenium based catalyst</searchLink> ) Array ( [Name] => Abstract [Label] => Description [Group] => Ab [Data] => 2,5-Bis-(hydroxymethyl)furan (BHMF) is an important biomass-based platform chemical that can be derived from the hydrogenation of biomass-based 5-hydroxymethylfurfural (HMF). In this paper, the formation of BHMF from HMF via the catalytic transfer hydrogenation (CTH) process, using isopropanol as the hydrogen source and Ru/Co3O4 as the catalyst, was studied. The results revealed that the Ru/Co3O4 catalyst displayed a high catalytic efficiency, and that a BHMF yield of up to 82% was obtained at 190 °C in 6 h. Moreover, it was found that the recovered Ru/Co3O4 exhibited a similar catalytic activity to the pristine Ru/Co3O4 catalyst. These results supported the conclusion that the present CTH process is an attractive green route for the synthesis of BHMF from biomass-based HMF. ) Array ( [Name] => TypeDocument [Label] => Document Type [Group] => TypDoc [Data] => text ) Array ( [Name] => Format [Label] => File Description [Group] => SrcInfo [Data] => application/pdf ) Array ( [Name] => Language [Label] => Language [Group] => Lang [Data] => English ) Array ( [Name] => NoteTitleSource [Label] => Relation [Group] => SrcInfo [Data] => Catalytic Materials; https://dx.doi.org/10.3390/catal7030092 ) Array ( [Name] => DOI [Label] => DOI [Group] => ID [Data] => 10.3390/catal7030092 ) Array ( [Name] => URL [Label] => Availability [Group] => URL [Data] => https://doi.org/10.3390/catal7030092 ) Array ( [Name] => Copyright [Label] => Rights [Group] => Cpyrght [Data] => https://creativecommons.org/licenses/by/4.0/ ) Array ( [Name] => AN [Label] => Accession Number [Group] => ID [Data] => edsbas.131D824A ) |
| RecordInfo |
Array
(
[BibEntity] => Array
(
[Identifiers] => Array
(
[0] => Array
(
[Type] => doi
[Value] => 10.3390/catal7030092
)
)
[Languages] => Array
(
[0] => Array
(
[Text] => English
)
)
[Subjects] => Array
(
[0] => Array
(
[SubjectFull] => biomass
[Type] => general
)
[1] => Array
(
[SubjectFull] => 5-hydroxymethylfurfural
[Type] => general
)
[2] => Array
(
[SubjectFull] => 2,5-bis-(hydroxymethyl)furan
[Type] => general
)
[3] => Array
(
[SubjectFull] => catalytic transfer hydrogenation
[Type] => general
)
[4] => Array
(
[SubjectFull] => ruthenium based catalyst
[Type] => general
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl)Furan over Ru/Co3O4
[Type] => main
)
)
)
[BibRelationships] => Array
(
[HasContributorRelationships] => Array
(
[0] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Ting Wang
)
)
)
[1] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Junhua Zhang
)
)
)
[2] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Wenxing Xie
)
)
)
[3] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Yanjun Tang
)
)
)
[4] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Daliang Guo
)
)
)
[5] => Array
(
[PersonEntity] => Array
(
[Name] => Array
(
[NameFull] => Yonghao Ni
)
)
)
)
[IsPartOfRelationships] => Array
(
[0] => Array
(
[BibEntity] => Array
(
[Dates] => Array
(
[0] => Array
(
[D] => 01
[M] => 01
[Type] => published
[Y] => 2017
)
)
[Identifiers] => Array
(
[0] => Array
(
[Type] => issn-locals
[Value] => edsbas
)
[1] => Array
(
[Type] => issn-locals
[Value] => edsbas.oa
)
)
[Titles] => Array
(
[0] => Array
(
[TitleFull] => Catalysts; Volume 7; Issue 3; Pages: 92
[Type] => main
)
)
)
)
)
)
)
|
| IllustrationInfo |