Academic Journal

Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl)Furan over Ru/Co3O4

التفاصيل البيبلوغرافية
العنوان: Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl)Furan over Ru/Co3O4
المؤلفون: Ting Wang, Junhua Zhang, Wenxing Xie, Yanjun Tang, Daliang Guo, Yonghao Ni
المصدر: Catalysts; Volume 7; Issue 3; Pages: 92
بيانات النشر: Multidisciplinary Digital Publishing Institute
سنة النشر: 2017
المجموعة: MDPI Open Access Publishing
مصطلحات موضوعية: biomass, 5-hydroxymethylfurfural, 2,5-bis-(hydroxymethyl)furan, catalytic transfer hydrogenation, ruthenium based catalyst
الوصف: 2,5-Bis-(hydroxymethyl)furan (BHMF) is an important biomass-based platform chemical that can be derived from the hydrogenation of biomass-based 5-hydroxymethylfurfural (HMF). In this paper, the formation of BHMF from HMF via the catalytic transfer hydrogenation (CTH) process, using isopropanol as the hydrogen source and Ru/Co3O4 as the catalyst, was studied. The results revealed that the Ru/Co3O4 catalyst displayed a high catalytic efficiency, and that a BHMF yield of up to 82% was obtained at 190 °C in 6 h. Moreover, it was found that the recovered Ru/Co3O4 exhibited a similar catalytic activity to the pristine Ru/Co3O4 catalyst. These results supported the conclusion that the present CTH process is an attractive green route for the synthesis of BHMF from biomass-based HMF.
نوع الوثيقة: text
وصف الملف: application/pdf
اللغة: English
Relation: Catalytic Materials; https://dx.doi.org/10.3390/catal7030092
DOI: 10.3390/catal7030092
الاتاحة: https://doi.org/10.3390/catal7030092
Rights: https://creativecommons.org/licenses/by/4.0/
رقم الانضمام: edsbas.131D824A
قاعدة البيانات: BASE