التفاصيل البيبلوغرافية
العنوان: |
Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl)Furan over Ru/Co3O4 |
المؤلفون: |
Ting Wang, Junhua Zhang, Wenxing Xie, Yanjun Tang, Daliang Guo, Yonghao Ni |
المصدر: |
Catalysts; Volume 7; Issue 3; Pages: 92 |
بيانات النشر: |
Multidisciplinary Digital Publishing Institute |
سنة النشر: |
2017 |
المجموعة: |
MDPI Open Access Publishing |
مصطلحات موضوعية: |
biomass, 5-hydroxymethylfurfural, 2,5-bis-(hydroxymethyl)furan, catalytic transfer hydrogenation, ruthenium based catalyst |
الوصف: |
2,5-Bis-(hydroxymethyl)furan (BHMF) is an important biomass-based platform chemical that can be derived from the hydrogenation of biomass-based 5-hydroxymethylfurfural (HMF). In this paper, the formation of BHMF from HMF via the catalytic transfer hydrogenation (CTH) process, using isopropanol as the hydrogen source and Ru/Co3O4 as the catalyst, was studied. The results revealed that the Ru/Co3O4 catalyst displayed a high catalytic efficiency, and that a BHMF yield of up to 82% was obtained at 190 °C in 6 h. Moreover, it was found that the recovered Ru/Co3O4 exhibited a similar catalytic activity to the pristine Ru/Co3O4 catalyst. These results supported the conclusion that the present CTH process is an attractive green route for the synthesis of BHMF from biomass-based HMF. |
نوع الوثيقة: |
text |
وصف الملف: |
application/pdf |
اللغة: |
English |
Relation: |
Catalytic Materials; https://dx.doi.org/10.3390/catal7030092 |
DOI: |
10.3390/catal7030092 |
الاتاحة: |
https://doi.org/10.3390/catal7030092 |
Rights: |
https://creativecommons.org/licenses/by/4.0/ |
رقم الانضمام: |
edsbas.131D824A |
قاعدة البيانات: |
BASE |