Academic Journal
Chemoenzymatic Hunsdiecker-Type Decarboxylative Bromination of Cinnamic Acids
| العنوان: | Chemoenzymatic Hunsdiecker-Type Decarboxylative Bromination of Cinnamic Acids |
|---|---|
| المؤلفون: | Li, Huanhuan (author), Younes, S.H.H. (author), Chen, Shaohang (author), Duan, Peigao (author), Cui, Chengsen (author), Wever, Ron (author), Zhang, Wuyuan (author), Hollmann, F. (author) |
| سنة النشر: | 2022 |
| المجموعة: | Delft University of Technology: Institutional Repository |
| مصطلحات موضوعية: | biocatalysis, decarboxylation, Hunsdiecker reaction, unsaturated carboxylic acids, vanadium chloroperoxidase, vinyl bromides |
| الوصف: | In this contribution, we report chemoenzymatic bromodecarboxylation (Hunsdiecker-type) of α,ß-unsaturated carboxylic acids. The extraordinarily robust chloroperoxidase from Curvularia inaequalis (CiVCPO) generated hypobromite from H2O2 and bromide, which then spontaneously reacted with a broad range of unsaturated carboxylic acids and yielded the corresponding vinyl bromide products. Selectivity issues arising from the (here undesired) addition of water to the intermediate bromonium ion could be solved by reaction medium engineering. The vinyl bromides so obtained could be used as starting materials for a range of cross-coupling and pericyclic reactions. ; BT/Biocatalysis |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| Relation: | http://www.scopus.com/inward/record.url?scp=85128216059&partnerID=8YFLogxK; ACS Catalysis--2155-5435--cca88431-0c6d-40d8-8727-04c974152c22; http://resolver.tudelft.nl/uuid:405f342d-f901-4259-ac5b-bbef8c023161; https://doi.org/10.1021/acscatal.2c00485 |
| DOI: | 10.1021/acscatal.2c00485 |
| الاتاحة: | http://resolver.tudelft.nl/uuid:405f342d-f901-4259-ac5b-bbef8c023161 https://doi.org/10.1021/acscatal.2c00485 |
| Rights: | © 2022 Huanhuan Li, S.H.H. Younes, Shaohang Chen, Peigao Duan, Chengsen Cui, Ron Wever, Wuyuan Zhang, F. Hollmann |
| رقم الانضمام: | edsbas.11DA4F45 |
| قاعدة البيانات: | BASE |
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