التفاصيل البيبلوغرافية
| العنوان: |
Layer-by-layer connection for large area single crystal boron nitride multilayer films |
| المؤلفون: |
Shi, Hui, Wang, Mingyuan, Chen, Hongying, Rousseau, Adrien, Shu, Junpeng, Tian, Ming, Chen, Ruowang, Plo, Juliette, Valvin, Pierre, Gil, Bernard, Qi, Jiajie, Wang, Qinghe, Liu, Kaihui, Zhang, Mingliang, Cassabois, Guillaume, Wu, Di, Wan, Neng |
| سنة النشر: |
2024 |
| المجموعة: |
Condensed Matter |
| مصطلحات موضوعية: |
Condensed Matter - Materials Science |
| الوصف: |
Boron nitride (BN) is today considered as one of the most promising materials for many novel applications including bright single photon emission, deep UV opto-electronics, small sized solid-state neutron detector, and high-performance two-dimensional materials, etc. Despite the recent successful fabrication of large-area BN single-crystals (typically <= 5 atomic layers), the scalable growth of thicker single-crystalline BN films still constitutes a great challenge. In this work, we demonstrate an approach to grow large-area multilayer single-crystal BN films by chemical vapor deposition on face-centered cubic Fe-Ni (111) single crystal alloy thin films with different stoichiometric phases. We show that the BN growth is greatly tunable and improved by increasing the Fe content in single-crystal Fe-Ni (111). The formation of pyramid-shaped multilayer BN domains with aligned orientation enables a continuous connection following a layer-by-layer, 'first-meet-first-connect', mosaic stitching mechanism. By means of selected area electron diffraction, micro-photoluminescence spectroscopy in the deep UV and high-resolution transmission electron microscopy, the layer-by-layer connection mechanism is unambiguously evidenced, and the stacking order has been verified to occur as unidirectional AB and ABC stackings, i.e., in the Bernal and rhombohedral BN phase. |
| نوع الوثيقة: |
Working Paper |
| URL الوصول: |
http://arxiv.org/abs/2404.08875 |
| رقم الانضمام: |
edsarx.2404.08875 |
| قاعدة البيانات: |
arXiv |