التفاصيل البيبلوغرافية
| العنوان: |
Structure, heat capacity and Raman spectra of mm-sized Ba$_{2}$MgWO$_{6}$ single crystals synthesized by BaCl$_{2}$-MgCl$_{2}$ flux method |
| المؤلفون: |
Pásztorová, Jana, Bi, Wen Hua, Gaal, Richard, Krämer, Karl, Živković, Ivica, Rønnow, Henrik M. |
| سنة النشر: |
2022 |
| المجموعة: |
Condensed Matter |
| مصطلحات موضوعية: |
Condensed Matter - Materials Science |
| الوصف: |
We present a new method of Ba$_{2}$MgWO$_{6}$ single crystal synthesis that allows to grow larger crystals using BaCl$_{2}$ and MgCl$_{2}$ flux. Difficulties to grow single crystal of a size suitable for macroscopic material property measurements caused the majority of characterisation being published on polycrystalline samples. Single crystal diffraction and energy dispersive X-ray analysis confirmed high quality of synthesised samples. Heat capacity measurements from 300~K to 2~K do not show any transitions. However, Raman spectra measured down to 77~K contain additional peaks at all temperatures probed, which is in a contrast with only 4 Raman active modes expected from the reducible representation. This calls for a more detailed study of potential symmetry breaking that could also influence the electronic properties of the material. |
| نوع الوثيقة: |
Working Paper |
| DOI: |
10.1016/j.jssc.2023.124184 |
| URL الوصول: |
http://arxiv.org/abs/2212.06270 |
| رقم الانضمام: |
edsarx.2212.06270 |
| قاعدة البيانات: |
arXiv |