Report
Epitaxial hexagonal boron nitride for hydrogen generation by radiolysis of interfacial water
| العنوان: | Epitaxial hexagonal boron nitride for hydrogen generation by radiolysis of interfacial water |
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| المؤلفون: | Binder, Johannes, Dąbrowska, Aleksandra Krystyna, Tokarczyk, Mateusz, Ludwiczak, Katarzyna, Bożek, Rafał, Kowalski, Grzegorz, Stępniewski, Roman, Wysmołek, Andrzej |
| المصدر: | Nano Letter 2023, 23, 4, 1267 - 1272 |
| سنة النشر: | 2022 |
| المجموعة: | Condensed Matter Physics (Other) |
| مصطلحات موضوعية: | Physics - Chemical Physics, Condensed Matter - Materials Science |
| الوصف: | Hydrogen is an important building block in global strategies towards a future green energy system. To make this transition possible, intense scientific efforts are needed, also in the field of materials science. Two-dimensional crystals, such as hexagonal boron nitride (hBN), are very promising in this regard, as it was demonstrated that micrometer-sized exfoliated flakes are excellent barriers to molecular hydrogen. However, it remains an open question whether large-area layers fabricated by industrially relevant methods preserve such promising properties. In this work we show that electron beam-induced splitting of water creates hBN bubbles that effectively store molecular hydrogen for weeks and under extreme mechanical deformation. We demonstrate that epitaxial hBN allows direct visualization and monitoring of the process of hydrogen generation by radiolysis of interfacial water. Our findings show that hBN is not only a potential candidate for hydrogen storage, but also holds promise for the development of unconventional hydrogen production schemes. |
| نوع الوثيقة: | Working Paper |
| DOI: | 10.1021/acs.nanolett.2c04434 |
| URL الوصول: | http://arxiv.org/abs/2211.01953 |
| رقم الانضمام: | edsarx.2211.01953 |
| قاعدة البيانات: | arXiv |
| DOI: | 10.1021/acs.nanolett.2c04434 |
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